Foreword (1.48mb) |
Abstract |
ii |
|
Executive Summary |
xi |
Section 1 (975kb) |
1 |
Introduction |
1 |
|
|
1.1 |
Project Objectives |
2 |
1.2 |
Project Tasks |
2 |
1.3 |
GTL Transportation Issues |
5 |
Section 2 (2.51mb) |
2 |
GTL Process Review |
7 |
|
|
2.1 |
Synthesis Gas Production |
7 |
|
2.1.1 |
Non-Catalytic Partial Oxidation of Natural Gas |
8 |
2.1.2 |
Steam Reforming |
8 |
2.1.3 |
Autothermal Reforming |
8 |
2.1.4 |
Process Evaluation |
9 |
2.2 |
Fischer-Tropsch Synthesis |
9 |
|
2.2.1 |
FT Synthesis In Fixed Bed Reactors |
10 |
2.2.2 |
Fluidized Bed FT Reactors |
10 |
2.2.3 |
Slurry Bed Reactors |
11 |
2.3 |
Range of Products |
13 |
|
2.3.1 |
The Fischer-Tropsch Process |
13 |
2.3.2 |
Type of Reactors |
16 |
2.3.3 |
Catalyst |
17 |
2.3.4 |
Pressure |
19 |
2.3.5 |
Temperature |
19 |
2.3.6 |
H2/CO Ratio |
19 |
2.3.7 |
Space Velocity |
19 |
2.4 |
FT Products Refining and Upgrading |
20 |
2.5 |
Summary |
22 |
Section 3 (3.05mb) |
3 |
GTL Material Testing |
24 |
|
|
3.1 |
GTL Material Testing |
24 |
Tables 3.1-3.11 (2.07mb) |
3.2 |
Quality Assurance Project Plan |
25 |
Figures 3.1-3.14 (4.09mb) |
3.3 |
Description of the Density and Viscosity
Measurement Apparatus |
26 |
|
|
3.3.1 |
Anton-Parr Densitometer |
26 |
3.3.2 |
Brookfield Rotational Viscometer |
26 |
3.4 |
Test Fluids for Density and Viscosity
Measurements |
27 |
|
3.4.1 |
Crude Oil Reconditioning and Aliquoting |
27 |
3.5 |
Test Conditions for Density and
Viscosity Measurements |
28 |
3.6 |
Experimental Procedures for Density and
Viscosity Measurements |
28 |
|
3.6.1 |
Density Measurements |
28 |
|
3.6.1.1 |
Calibration |
28 |
3.6.1.2 |
Test Sample Density Measurement |
30 |
3.6.2 |
Viscosity Measurements |
30 |
|
3.6.2.1 |
Calibration |
30 |
3.6.2.2 |
Test Sample Viscosity Measurement |
31 |
3.7 |
Experimental Results and Discussions |
33 |
|
3.7.1 |
Density Measurements |
33 |
3.7.2 |
Viscosity Measurements |
34 |
3.8 |
Correlations of the Measured Density and
Viscosity Data |
34 |
3.9 |
Test Fluids for Gel Strength
Measurements |
36 |
|
3.9.1 |
GTL 1 |
36 |
3.9.2 |
GTL 2 |
36 |
3.10 |
GTL and Taps Crude Oil Blends |
36 |
3.11 |
Compositional Analysis of GTL 1 and
Crude Oil Blends |
37 |
3.12 |
Compositional Analysis of GTL 2 and
Crude Oil Blends |
38 |
3.13 |
Test Temperatures for Gel Strength
Measurements |
38 |
3.14 |
Gel Strength Measurement Procedure |
38 |
3.15 |
Experimental Results and Discussions |
39 |
|
3.15.1 |
Gel Strength Measurements on GTL 1 and
TAPS Crude Oil |
39 |
3.15.2 |
Gel Strength Measurements on GTL 2 and
TAPS Crude Oil |
40 |
3.16 |
Comparison of Gel Strength Measurements
on GTL 1 and GTL 2 and TAPS Crude Oil Blends |
41 |
3.17 |
Conclusions |
41 |
|
3.17.1 |
Density and Viscosity Measurements |
41 |
3.17.2 |
Gel Strength Measurements |
42 |
Section 4 (2.57mb) |
4 |
Hydraulic Modelling of GTL
Transportation |
66 |
|
|
4.1 |
Batch Flow |
66 |
4.2 |
Commingled Flow |
68 |
4.3 |
Development of Model Equations |
69 |
|
4.3.1 |
Batch Flow Model |
69 |
|
4.3.1.1 |
Assumptions |
69 |
4.3.1.2 |
Governing Equations |
69 |
4.3.2 |
Commingled Flow Model |
76 |
4.4 |
Application of Model Equations |
80 |
|
4.4.1 |
Calculation Algorithm |
80 |
|
4.4.1.1 |
Batch Flow |
80 |
4.4.1.2 |
Commingled Flow |
81 |
4.5 |
Results |
82 |
4.6 |
Conclusions |
85 |
Section 5 pt. 1 (3.32mb) |
5 |
Thermodynamics of GTL Transportation |
90 |
|
|
5.1 |
Heat Transfer Analysis |
90 |
|
5.1.1 |
Below Ground Pipe Line |
90 |
5.1.2 |
Above Ground Pipe Line |
98 |
5.2 |
Fluid Dynamic Analysis |
101 |
5.3 |
Pipeline Specifications and Fluid
Properties |
102 |
|
5.3.1 |
Pipe Specifications |
102 |
5.3.2 |
Fluid Properties |
104 |
5.3.3 |
Properties of Air |
106 |
Section 5 pt. 2 (4.10mb) |
5.4 |
Heat Transfer Calculations |
110 |
|
5.5 |
Results and Discussion |
110 |
|
5.5.1 |
Heat Transfer Parameters |
110 |
5.5.2 |
Heat Loss From TAPS |
112 |
5.5.3 |
Exit Temperature of the Fluid from TAPS |
114 |
5.5.4 |
Exit Temperature of Fluid in Various
Months |
115 |
5.5.5 |
Heat Loss From Aboveground and
Belowground Sections of the Pipeline |
118 |
5.5.6 |
Comparison of Actual Data and Calculated
Results |
122 |
5.6 |
Conclusions |
125 |
Section 6 (3.25mb) |
6 |
Economics of GTL Transportation through
TAPS |
129 |
|
|
6.1 |
Introduction |
129 |
6.2 |
GTL Transportation Modes |
129 |
|
6.2.1 |
Commingled Mode |
129 |
6.2.2 |
Batch Mode of Transportation |
130 |
|
6.2.2.1 |
Batch Mode A |
130 |
6.2.2.2 |
Batch Mode B |
131 |
6.2.2.3 |
Batch Mode C |
132 |
6.3 |
Economic Parameters |
133 |
6.4 |
Identifying Capital and Operating Costs |
133 |
|
6.4.1 |
Plant Cost |
134 |
6.4.2 |
Storage, Product Separation and Other
Costs |
136 |
6.4.3 |
Energy Cost |
137 |
6.4.4 |
Cost of Upstream Natural Gas |
138 |
6.4.5 |
The TAPS Tariff |
140 |
6.4.6 |
Taxes |
143 |
|
6.4.6.1 |
Property Tax (ad Valorem) |
143 |
6.4.6.2 |
State Corporate Income Tax |
143 |
6.4.6.3 |
Severance Tax |
143 |
6.4.6.4 |
Federal Corporate Income Tax |
143 |
6.5 |
GTL Product Premium |
143 |
6.6 |
Sensitivity Analysis |
145 |
6.7 |
Method of Evaluation |
147 |
|
6.7.1 |
Investment Pattern |
147 |
6.8 |
Results and Discussion |
147 |
6.9 |
Summary and Conclusions |
153 |
Section 7 (590kb) |
7 |
Conclusions and Recommendations |
156 |
|
|
7.1 |
Conclusions |
156 |
7.2 |
Recommendations |
159 |
|
Appendix A (2.16mb) |
APPENDIX A |
Quality Assurance Project Plan |
161 |
Attachment 1 pt. 1 (2.38mb)
Attachment 1 pt. 2 (2.13mb)
Attachment 1 pt. 3 (1.91mb) |
ATTACHMENT 1 |
Evaluation of GTL #1 and Blends by WTC |
Attachment 2 pt. 1 (2.06mb)
Attachment 2 pt. 2 (2.43mb) |
ATTACHMENT 2 |
Evaluation of GTL #2 and Blends by WTC |