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T. O. M. Microfilm Reel 027

(Original Identification Reel 27A)

 

Table of Contents

 

 

Note from the editors – only selected documents from this microfilm reel have been completely processed and presented below in cleaned and grouped format (Bag 2196, Sections (c), (d), and (f) only, identified by HTML links).  The remainder of the reel is not related to the Fischer-Tropsch process, and therefore complete processing cannot be justified at this time.

 

We are, however, making the entire reel contents available in raw image format, although in a small number of relatively large files (rather than a very large number of small individual images).  Anyone interested in pursuing the non-FT related material on this reel may find the document in these larger raw files.

 

                                                Images 0001-0100                               File size ca. 40 Mb

                                                Images 0101-0200                               File size ca. 40 Mb

                                                Images 0201-0300                               File size ca. 33 Mb

                                                Images 0301-0400                               File size ca. 27 Mb

                                                Images 0401-0500                               File size ca. 31 Mb

                                                Images 0501-0600                               File size ca. 28 Mb

                                                Images 0601-0658                               File size ca. 35 Mb

 

 

Bag 2169, Target 30/4.03 – Ludwigshafen

                                               

(a)   Catalyst Manufacture and Properties              

1.                  Supply of sodium sulfide for sulfigran

2.                  Life of brown oxide catalyst

                3.                 Preparation of xircon oxide gel

                4.                  Preparation of Tonalon (Water-soluble alumina)

5.                Preparation of N-catalyst for ammonia oxidation

6.                Preparation of B.S. catalyst

                7.                  Preparation of B.Z. catalyst

                8.                  Brown oxide catalys plant for Frose

                9.                  Sketch of B.S. and B.Z. manufacture

                10.                  Flow sheet for B.Z. Catalyst manufacture

11.                  Order for rotary kiln

12.                  Metal requirements for Frose catalyst plan

13.                  Drawings of Frose Catalyst plant

14.                  Miscellaneous information on brown oxide catalyst manufacture at Frose and Gapel

15.                Operating description of brown oxide catalyst plant

 

(b)    Manufacture of Ethylene Glycol from Methylacetal, CO and Hydrogen

16.                  Inspection of Leuna Formaldehyde Plant

17.                  Production of Vanol

 

(c)     H2S Absorption on Activated Charcoal

18.                  Cost estimate for a desulfurization plant.  September 27, 1941.  3 pages.

19.                  Description of plant for gas desulfurization (Scholven III).  July 1941.  9 pages.

20.                  Flow sheets of activated charcoal desulfurization.  3 pages.

21.                  Request for Bidon desulfurization plant.  January 18, 1939.  2 pages.

22.                  Activated charcoal plant for Scholven.  June 1, 7, and 17, 1939.  5 pages.

23.                  Conference and notes on desulfurization of water gas (Scholven III).  June and July, 1939.  18 pages.

24.                  Desulfurization (Scholven III and Brux).  July 7, 1939.  2 pages.

25.                  F- and M- Charcoal absorption, Waldenburg.  September and October, 1943.  2 pages.

26.                  Desulfurization plant for Brux.  June 29, 1939.  4 pages.

27.                  Desulfurization at Leuna.  March 7, 1940.  2 pages.

 

(d)     Hydrocarbon Synthesis Starting with CO and Hydrogen (Fischer-Tropsch)

28.                  Description of I.G. Fischer-Tropsch.  By Schlecht, et al. February 16, 1943.  2 pages.

29.                  Cobalt Supply Situation.  By Dr. Altpeter.  February 16, 1943.  1 page.

30.                  Priority certificate for experimental CO and H2 plant.  3 pages.  Very poor legibility.

31.                  Berlin conference on CO-H2 Synthesis.  September 15, 1942.  2 pages.

                32.                  CO + H2 synthesis with oil recirculation.  January 5, 1942.  2 pages.

                33.                  Catalyst for Hydrocarbon Synthesis.  Undated.  3 pages.

 

(e)      Difficulties with Iso-octane from Heydebreck

34.                  High Pour Point Difficulties with Iso-octane

                35.                  High Pour Point Difficulties with Iso-octane

 

(f)      Manufacture of Industrial Gases

36.                  Emergency measures for gas production.  July 4, 1944.  9 pages.

37.                  Gas manufacture at Oppau.  June 25, 1943.  Production tables and plant flow sheets.  11 pages.

38.                  Condensation of water from hydrogen manufacture.  By Dr. Sachsse.  December 5, 1942.  24 pages.

39.                  Experiments on CO conversion.  By Dr. Friederici.  February 26, 1941.  6 pages.

40.           Operation of hydrocarbon synthesis (Fischer-Tropsch) gas plant, 1941.  By Dr. Sachsse.  January 16, 1942.  7 pages.

            41.                  Preparation of synthesis gas.  March 18, 1941.  3 pages.

                42.           Comparison of plant costs, operating costs, and steel requirements of hydrogen plants of the atmospheric and high pressure type.  Mineralol-Baugesellschaft M. B. H.  February 20, 1939.  30 pages.

 

(g)      Substances for Gasproofing of Textiles

43.                  Method for increasing the efficiency of gas proofing materials

                43a.                 Gasproof fabrics

                44.                  Gasproof fabrics

                45.                  Gasproof fabrics

                46.                  Gasproof fabrics

                                   

(h)      Miscellaneous

47.           Order for experimental work on the reactions of olefins with CO and H2 in the presence of sodium salt of sulfanilic acid

48.                  Order for experimental work on the dehydrogenation of light hydrocarbons with fixed bed catalysts

                49.                  Order for experimental work for the preparation of synthetic fats, fatty acids and glycerine

                50.                  Order for experimental work on the preparation of Toluene with chlormethyl and benzene

                51.                  Preparation of water emulsions of polyisobutylene

                52.                  Continuous production of Polyisobutylene

                53.                  Fuming acid for artifical fog

                54.                  Removal of artifical fog from intake to air compressors

                55.                  Conference on analytical determination of olefins

                56.                  Drying with silica gel

                57.                  Experiments on the drying of liquids with silica gel

 

Bag 2007, Target 30/4.03 - Ludwigshafen

 

(a)     Analytical Methods and Physical and Chemical Data

1.                  Definition of carbonyl and acetyl number

2.                  Determination of carbonyl groups in aldehydes and ketones

3.                  Table of vapor pressure of methylbutandiol – 1,4

4.                  Determination of 1,4-butanediol in crude solution

5.                  Heat of combustion of some nitriles, acids and esters.

6.                  Analysis of di-isobutylene

7.                  Vapor pressure of tetrahydrofuren containing water and nickel carbonyl

 

(b)  Preparation and Utilization of Pimelic Acid   

8.                  Use of the hexamethylenediamine salt of pimelic acid for the manufacture of bristles

9.                  Use of pimelic acid in the manufacture of polyamides

10.                  Use of pimelic acid in the manufacture of polymides

11.                  Ethylhexanol esters of pimelic and related acids as

12.                  Process for the manufacture of pimelic acid

13.                  Preliminary economic balance of pimelic acid manufacture

                                 

(c)     Explosion Experiments on Acetylene and its Derivatives

14.                  Explosion experiments on mono- and divinylacetylene

15.                  Effect if tube diameter and wall thickness on the propagation of a detonation wave

16.                  Explosion experiments on acetylene

 

(d)    Problems of the Butadiene Manufacture

17.                  Continuous distillation plant at Schkopau

18.                  Removal of SiO2 from crude butynediol solution

 

(e)     Manufacture and Utilization of Propargyl Alcohol

19.                  Rust remover PL (Propargyl-alcohol – HC1)

20.                  Plant distillation of propargylalcohol

21.                  Effect of aqueous propargyl alcohol containing formic acid on iron

22.                  Flow sheet for separation of propargyl alcohol from formaldehyde by distillation

23.                  Proposed mathod of manufacture of allylalcohol from propargyl alcohol

 

(f)     Chemical Engineering Investigations

24.                  Investigations on bubble plate designs

25.                  Investigations on driers

26.                  Investigations on filters

27.                  Various investigations on chemical engineering apparatus

 

(g)     Preparation of Organic Chemicals

28.                  Patent application on the preparation of derivatives of –3 tetrahydrobenzoic acid

29.                  Patent application on the preparation of salts of hydroxycarboxylic acids

30.                  Recycle butadiene from the Buna Polymerization as basis for new manufacturing processes

31.                  Patent application on the preparation of diol derivatives

32.                  Part of patent application on the preparation of nitriles

33.                  Patent application on the manufacture of carboxylic acids

34.                  Patent application on the manufacture of carboxylic acids

 

(h)   Drawings on Manufacture of Chemicals for Synthetic Rubber

 

Tetrahydrofuran

 

Drawing No.                                          Title

 

35.  L-15175a-2                 Tetrahydrofuran Distillation

36.  L-6119b-1                   Tetrahydrofuran Reactors

37.  L-6120b-1                   Tetrahydrofuran Reactors

 

    Ethylbenzene Styrene

 

38.  L-15606a-2                 Alkylation

39.  L-15607a-2                 Alkylation

40.  L-6083a-2                   Benzene-Ethylbenzene Distillation

41.  L-5884a-1                   Ethyl Benzene Dehydrogenation

42.  L-4225c-1                   Styrene Distillation

43.  L-14407b-2                 Styrene Distillation

 

Butane-diol Distillation

 

44.  L-15715-2                   Material Balance

45.  L-5202a-1                   Apparatus

46.  An19a                     Flowsheet

47.  L-5707                        Apparatus & Piping

48.  L-5204a-1                   Building

49.  L-13471f-2                 Flowsheet – one reactor cell

50.  L-5769d-1                   Reaction chamber

51.  L-4118a-1                   Degasification column

52.  L-5167e-1                   Degasification Flowsheet

53.  L-5481e-1                   Acetylene Pumps

54.  L-5861e-                     Piping-Elmo chamber

55.  L-6328b-8                   Flowsheet-acetylene residue gas wash

 

Butynediol Distillation

 

56.  Lu-128                          Material Balance

57.  IN 22e                          Flow Diagram

58.  In 25a                          Detail flowsheet

59.  L-5201d-1                   Flowsheet

60.  L-5675f-1                   Tankage

61.  SK 2/1/45                      New Flowsheet

62.  - - -                                   New plot plan

63.  L-13532b-2                 Plot plan

64.  L-5167C-1                  Degasification

 

      Aldol Condensation of Acetaldehyde

 

65.  L-5942a-1        Flowsheet

66.  L-5943a-1                   Reactors

67.  L-5944a-1                   Distillation

68.  L-5052b-1                   Piping

69.  N-12280C-2                                Flowsheet (proposal)

 

End of Reel 027.