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Technology Development For Iron Fischer-Tropsch Catalysts.
Final Technical Report - 1993

Davis, B. H.

University of Kentucky

Cover Page
Summary

Section 1
358kb

A Survey of Literature For The Preparation, Activation and Testing of Precipitated Iron Fischer-Tropsch Catalysts

Section 2 Theory of Precipitation
Section 3 Preparation Procedures for Specific Iron Hydroxide and Oxide Compounds
Section 4 Preparation of Iron Catalysts. Experimental
Table of Contents 34kb
Summary 179kb
Part 1
1,548kb
Iron Fischer-Tropsch Catalyst. A Study of the Oxidation of Ferrous Hydroxide in Slightly Basic Solution to Produce y-FeOOH.
Part 2
2,286kb
Iron Fischer-Tropsch Catalysts. Structural Features in the Formation of the Green Rust Intermediate and y-FeOOH.
Part 3
1,525kb
Preparation of δ-FeOOH. Oxidation of Fe2+ in Strongly Basic Conditions.
Part 4
1,566kb
Iron Fischer-Tropsch Catalysts: Preparation by Oxidation of Aqueous Suspension of Fe(OH)2.
Part 5
947kb
Influence of EDTA on the Formation of y-FeOOH.
Part 6
765kb
Promoted Iron Fischer-Tropsch Catalysts. Characterization by Nitrogen Sorption.
Part 7
763kb
Promoted Iron Catalysts. Characterization by Thermal Analysis.
Part 8
569kb
Cation Adsorption by Hydrous Iron Oxides.
Part 9
1,233kb
Iron Fischer-Tropsch Catalyst. Preparation of y-FeOOH Form Ferric Salt Solutions.
Part 10
1,071kb
Pilot Plant for Preparation of 100 lb/week of Iron Catalyst and the Preparation of 100 Pounds of Catalyst for PETC.
Section 5 Chemical and Physical Changes During and Induction Period
Section 6 Summary 193kb
Part 1
994kb
Fischer-Tropsch Synthesis: Impact of Pretreatment of Ultrafine Iron Oxide Upon Catalyst Structure and Selectivity
Part 2
947kb
Fischer-Tropsch Synthesis: Mössbauer Studies of Pretreated Ultrafine Iron Oxide Catalysts
Part 3
1,114kb
Iron Fischer-Tropsch Catalysis - Properties of an Ultrafine Iron Oxide Catalyst
Part 4
1,146kb
Fischer-Tropsch Synthesis: Impact of Potassium and Zirconium Promoters on the Activity and Structure of an Ultrafine Iron Oxide Catalyst
Part 5
1,261kb
Activation and Characterization Studies of Commercial Fischer-Tropsch Iron Catlysts
Part 6
486kb
CO Pretreatment of an Iron Based Fischer-Tropsch Catalyst in the Slurry Phase: Comparison of CSTR and Bubble Column Reactors
Part 7
2,323kb
Compositional Changes and Characterization of Precipitated Fischer-Tropsch Catalysts in the Slurry Phase Synthesis
Part 8
538kb
Fischer-Tropsch Synthesis and XRD Characterization of an Iron Carbide Catalyst Synthesized by Laser Pyrolysis
Part 9 1,113kb Fischer-Tropsch Catalysts. Attrition of Carbided Iron Catalyst in the Slurry Phase
Part 10
550kb
Surface Area and Porosity Changes in Iron Catalysts During Activation and Initial Use in the Fischer-Tropsch Synthesis
Section 7 Mechanistic Implications of the Chemisorption of CO and H2 in the Fischer Tropsch Synthesis
Section 8 Promoters for Iron Catalysts 1,062kb
Section 9 Summary 697kb
Part A
19kb
Introduction
Part B
438kb
Analysis of Fischer-Tropsch Synthesis Products
Part C
1,120kb
Iron Fischer-Tropsch Catalysis - Properties of an Ultrafine Iron Oxide Catalyst
Part D
2,008kb
Promoter Levels - Activity and Aging
Part E
1,376kb
Effect of Vapor-Liquid Equilibrium on Fischer-Tropsch Hydrogenation Selectivity From a Slurry Reactor For a Deactivating Catalyst
Part F
1,280kb
Reaction Rates and Kinetics of the Fischer-Tropsch Synthesis Over an Iron- Based Catalyst
Part G
1,024kb
Selectivity For the Conversion of Syngas
Part H
506kb
Process Considerations Based on Catalysts Performance