Back To TOM Reel Index

T.O.M. Microfilm Reel 254

(Original designation BM-40)

Table of Contents

Note from the editors - only selected documents from this microfilm reel have been completely processed and presented below in cleaned and grouped format (Section XXVI items 58 and 65, and Section XXVII Items 6 and 8 only, identified by HTML link below).  The remainder of the reel is not related to the Fischer-Tropsch process, and therefore complete processing cannot be justified at this time.

We are, however, making the entire reel contents available in raw image format, although in a small number of relatively large files (rather than a very large number of small individual images).  Anyone interested in pursuing the non-FT related material on this reel may find the document in these larger raw files.

Images 0001-0200                 File size ca.   47 Mb

Images 0201-0400                 File size ca.   50 Mb

Images 0401-0572                 File size ca.   54 Mb

Index to microfilm of Dr. Pier’s files

XXVI.   Vapor phase – hydrogenation.

Item No.

20.           Basis for evaluation of aromatization research.  Frames 1-4

21.           Troubles in vapor phase stalls.  Frames 5-7

22.           45 atm. aromatization with deteriorating activity.  Frames 8-11                      

23.           Saturation with 7846 catalyst.  Frame 12

24.           H2S addition in vapor phase.  Frames 13-16

25.           Semi technical work on saturation of bituminous coal hydrogenation middle oil and gasoline over 7846W250.  Frames 17-39

26.           The activity peak with 5058.  Frame 40

27.           Data (descriptive) on different catalysts.  Frames 41-47

28.           Catalytic behavior of the system cilicic  acid-alumina-iron during hydro-carbonization conversion reactions.  Frames 48-49

29.          Research results with tungsten catalysts.  Frames 50-52

30.           Splitting catalyst for catalytic high  pressure hydrogenation.  Frames 53-54

31.           ANIC catalysts.  Frames 55-56

32.           Gasoline quality for the Japanese plant.  Frames 57-59

33.           About catalyst 7846W250.   Frames 60-65

34.          Aromatization at 250 atm. with alumina- fuller’s earth catalyst 8688.  Frames 66-73

35.          Operations with 7846 and 5058 catalysts.  Frames 74-79

36.           Effect of oil partial pressure, throughput  and contact time on the results of saturation with 7846.  Frames 80-91            

37.           New splitting catalysts.  Frames 92-103

38.          Translations from Russians – “Recovery of high octane gasoline by hydrogenation.”  Frames 104-130                

39.           Influence of sulfur with fuller’s earth- iron fluoride catalysts.  Frames 131-134

40.           Production of hydrocarbon gases by hydrogenation.  Frames 135-138

41.           Crystal structure and X-ray investigations of tungsten sulfide structure.  Frames   139-140

42.            Reactions which do not alter the carbon skeleton.  Frame 141                                                              

43.           WS2 as technical catalyst and chemical compound (physical data).  Frames 142-144                                                                      

44.           Electron-diffraction relations of WS2.  Frames 145-146

45.           On the question of the existence of an amorphous intermediate state in the production of WS2 catalyst from ammonia-sulfo-tungstate.  Frames 147-148                           

46.           Historical development of catalysts  (chronology).  Frames 149-151

47.           Use of Mo and W sulfides as catalysts for pressure hydrogenation.  Frames 152-160

48.           Influence of added nitrogen compounds on the results when splitting petroleum gas oil over 6434.  II.  Frames 161-162                         

49.           Testing new saturation catalysts.  Frames 163-166

50.           Testing of composite samples of 5058,  8376, 6434.  Frames 167-169

51.           The temperature-dependence of reactions  which occur in the hydrogenation of bituminous coal liquefaction middle oil over 5058, 7846 and 8376 (7846W250).  Frames 170-185

52.           Exchange of experience on saturation catalyst 8376.  Frames 186-206                                   

53.           Processing crude oil by pressure distillation and cracking at 50 atm.  Frames 207-209

54.           Tungsten carbide as a hydrogenation catalyst.  Frames 210-212

55.           Saturation of Leuna gasoline and middle oil with the new 7846 catalyst.  Research in 200 cc. converter.  Frames 213-225

56.           Use of 8676 (7846W250) for various products.  Frames 226-242

57.           Position taken on the fluoride-patent of the ANIC catalyst.  Frames 243-245

58.           Catalytic cracking at low pressure and in presence of H2 at 45 atm.  By Free.  July 31, 1941.  Frames 246-252.  7 pages. 

59.           Politz problem of common processing of petroleum residues and bituminous coal tar-a-middle oil in the gas phase.  Frames 253-268

60.           Production of low endpoint (100°C.) gasoline (due to scarcity of iso-octane).  Frames 269-274

61.           Aromatization of middle oil from bituminous coal liquid phase.  Frames 275-277

62.           600 atmospheres aromatization.  Frames 278-280

63.           Further research in the domain of alumina- Mo-Ni catalysts.  Frames 281-288

64.           Research to refine heavy benzol with  alumina-Mo-Ni catalyst in 1 liter converter.  Frames 289-297

65.           Splitting Fischer-Tropsch high molecular weight paraffins over 5058 and 8376 at 250 atm.  By Peters and Mesee (?)  May 22, 1943.  Frames 298-302.  7 pages.

66.           Effect of temperature on yield with various concentrations of saturation catalysts.  Frames 303-304

67.           Reducing tungstic acid.  Frames 305-306 

68.           How to make 6434 catalyst.  Frames 307-308

69.           Splitting and DHD treatment of bituminous coal middle oil over saturation catalyst 7846W250.  Frames 309-326

70.           Splitting and isomerization of iso-octane and N-heptane over 5058.  Frame 327

71.           Action of sulfur in high pressure hydrogenation.  Frames 328-329

72.           Analytical evaluation of WS2 catalyst.  Frames 330-332

73.           Leuna discussion of catalysts.  Frames 333-338

74.           Comparison  of splitting of natural    fuller’s earth and synthetic silicates at 250 and 600 atm.  Frames 339-348                                   

75.           Aromatization of dephenolized middle  oil (Scholven) over 7019.  Frames 349-356

76.           Tests of feed stocks of different origin  for 7019.  Frames 357-358

77.           Comparison between natural fuller’s earth  (6109) and synthetic aluminum silicate (6752) at 600 atm.  Frames 359-363

78.           Influence of temperature and throughput in the one step 600 atm. aromatization of bituminous coal liquefaction middle oil with fuller’s earth catalyst.  Frames 364-371

79.           Calculations on the question of 300 vs.  700 atm.  Frames 372-374

80.           High load gasoline from bituminous coal using DHD as final step.  Frame 375

81.           Crystal structure of WS2 catalyst.  Frames 376-381

82.           Effect of recycle rate on 250 atm. aromatization of middle oil from bituminous coal liquefaction over alumina-fuller’s earth catalyst 8688.  Frames 382-390

83.           Aromatization at 250 atm. with alumina-fuller’s earth catalyst of the 8688 type.  Frames 391-404

84.           Splitting catalysts from iron sulfide on fuller’s earth.  Frames 405-409

85.           Variation of knock rating with different distillation fraction in 250 atm. splitting over 6434 catalyst.  Frames 410-417

86.           The ANIC fluoride catalyst compared with  6434.  Frames 418-423

87.           Discussion on ANIC catalyst operations.  Frames 424-426

88.           Comparison of 6434 and 6752 in aromatization processes.  Frames 427-432

89.           Activity of various alumina-W-Ni catalysts for hydrogenation.  Frames   433-438

90.           2-stage 300 atm. gas phase gasoline from various raw material and with various saturation catalyst.  Frames 439-445

91.           Sulfur addition in splitting over 6434.  Frames 446-448

92.           Action of W, V, Ni, Co, and Fe as active components on alumina saturation catalysts.  Frames 449-457

93.           Influence of the carrier on the results of 6434 splitting.  Frames 458-461

94.           Heavy oil splitting over fixed catalysts at 250-600 atm.  Frames 462-473

95.           Hydrogenation of crude wax.   Frames 474-475

96.           Catalyst test for the MoO2 operation of Ludwigshafen.  Frames 476-477

97.           Reasons for difference in quality of residue gasoline from aromatization.  Frames 478-487

XXVII.  Various organic processes.

1.             Hydrogenative splitting of natural rubber and buna.  Frames 489-490

2.               Synthesis of branched hydrocarbons  (tri-alkylcarbinol).  Frames 491-493

3.                Processes for high test pure hydrocarbons.  Frames 494-496

4.             Process for condensation products.  Frames 497-503

5.                Polybutylene rubber.  Frames 504-511

6.             Making alcohol from Michael Process products.  By Bueren.  February 3, 194.  Frames 512-515.  4 pages.

7.             WS2 for perhydrogenation of polynuclear aromatics.  Frames 516-525

8.             Literature survey on treatment of various hydrocarbons with hydrogen.  No author given.  May 27, 1943.  Frames 526-529.  4 pages.

9.             Ketone and hydrocarbon synthesis using AlCl3 and CaCl3.  Frames 530-532

10.           Hydrogenation of isobutyron over catalyst  7878.  Frames 533-537