|
Summary |
6 |
|
Results and Discussions |
8 |
|
|
I. |
Palladium Catalyst |
8 |
|
|
1. |
Preparation |
8 |
|
|
2. |
Continuous Flow Results |
9 |
|
Figure |
10 |
|
|
II. |
Cobalt Catalyst |
16 |
|
|
1. |
Preparation |
16 |
|
2. |
Static Reactions for Carbon Dioxide |
16 |
|
3. |
Continuous Reaction for Carbon Dioxide |
18 |
|
|
A. |
Reactions at Various Temperatures |
18 |
|
B. |
Reactions at various Flow Rates |
20 |
|
C. |
Reactions at Various Reactant Ratios |
20 |
|
D. |
Reactions in Relationship to Sulfur Dioxide Poisoning |
20 |
|
4. |
Continuous Reactions of Carbon Monoxide |
20 |
|
Table |
25 |
|
Experimental |
31 |
|
I. |
Equipment |
31 |
|
II. |
Materials |
32 |
|
III. |
Preparation of Catalyst |
32 |
|
|
1. |
Palladium |
32 |
|
2. |
A cobalt catalyst prepared from aqueous solutions |
33 |
|
3. |
Cobalt Catalyst by Immersion Process |
33 |
|
4. |
Cobalt Catalyst by Flash Evaporation |
33 |
|
5. |
Preparation of Unsupported Cobalt Catalyst |
34 |
|
6. |
Determination of Catalyst Loading on Support |
34 |
|
IV. |
Static Reactions with Cobalt |
35 |
|
|
1. |
Hydrogenation of Carbon Dioxide |
35 |
|
2. |
Hydrogenation of Carbon Monoxide |
35 |
|
V. |
Continuous Reactions |
35 |
|
VI. |
Analysis |
36 |
|
|
1. |
Qualitative |
36 |
|
2. |
Quantitative Analysis |
36 |
|
VII. |
Palladium Recovery Procedures |
37 |
|
VIII. |
Blank Runs |
38 |
|
References |
39 |
