Section 1 555kb |
List of Tables |
vi |
List of Figures |
viii |
Abstract |
xv |
I |
Objective and Scope of Work |
I-1 |
II |
Summary |
II-1 |
|
A |
Background |
II-1 |
B |
Results |
II-2 |
III |
Introduction |
III-1 |
IV |
Task 1 - Process Studies in Two-Stage
Bench-Scale Unit |
IV-1 |
|
A |
Bench-Scale Unit Modifications |
IV-1 |
B |
Preliminary Evaluation of a New
Fischer-Tropsch Catalyst in a Small Bubble-Column Reactor |
IV-5 |
Section 2 429kb |
C |
Other Supporting Studies |
IV-12 |
D |
Run CT-256-6 |
IV-22 |
Section 3 500kb |
E |
Run CT-256-7 |
IV-36 |
F |
Run CT-256-8 |
IV-50 |
Section 4 424kb |
G |
Run CT-256-9 |
IV-61 |
H |
Run CT-256-10 |
IV-72 |
I |
Run CT-256-11 |
IV-76 |
Section 5 408kb |
J |
Improvement of Catalyst Suspension in
Bubble-Columns Using UPward Slurry Circulation - Mathematical Model
Calculations |
IV-82 |
K |
Bench-Scale Unit Modifications and Run
CT-256-12 |
IV-85 |
L |
Run CT-256-13 |
IV-94 |
Section 6 414kb |
V |
Task 2 - Scoping Studies of
Fischer-Tropsch Reactor-Wax Upgrading |
V-1 |
|
A |
Reactor-Wax Vacuum Fractionation |
V-1 |
B |
Thermal Cracking of a Fishcer-Tropsch
Reactor-Wax Vacuum Bottom |
V-2 |
C |
Other Scoping Studies |
V-7 |
VI |
Task 3 - Product Evaluation |
VI-1 |
|
A |
Reactor-Wax Analyses by Gel Permeation
Chromatography |
VI-1 |
B |
Modified Gas Chromatography for Reactor-Wax
Analyses |
VI-1 |
C |
Field Ionization Mass Spectrometry for
Reactor-Wax Analyses |
VI-4 |
Section 7 398kb |
D |
Analyses of Oxygenates in Fischer-Tropsch
Reactor-Waxes |
VI-18 |
E |
Routine Product Analyses |
VI-19 |
VII |
Task 4 - Slurry Fischer-Tropsch
Reactor Hydrodynamic Studies |
VII-1 |
|
A |
Literature Review |
VII-1 |
B |
Pressure Drop Across orifice-Type Feed-Gas
Distributors |
VII-11 |
Section 8 559kb |
C |
Scoping Studies Using Small Hot-Flow Bubble
Columns |
VII-16 |
Section 9 199kb |
D |
Design and Construction of Two Tall,
Hot-Flow, Non-Reacting Bubble Columns |
VII-44 |
Section 10 722kb |
E |
Hydrodynamic Studies Using 5.1 and 10.2 cm ID
Tall, Hot-Flow Bubble-Columns |
VII-52 |
Section 11 703kb |
F |
Evaluation of Continuous Stirred-Tank
Reactors Using Mathematical Models |
VII-92 |
VIII |
Task 5 - Development of
Conceptual Process Schemes |
VIII-1 |
|
A |
Introduction |
VIII-1 |
B |
Design Base Data for Slurry
Fischer-Tropsch/ZSM-5 Unit |
VIII-2 |
C |
Conceptual Process Schemes |
VIII-6 |
Section 12 243kb |
IX |
Recommendations for Future
Schemes |
IX-1 |
X |
Nomenclature |
X-1 |
XI |
Reference |
XI-1 |
Section 13 555kb |
|
Appendix A: Summary of Data
from Run CT-256-6 |
Appendix B: Summary of Data
from Run CT-256-7 |
Section 14 543kb |
Appendix C: Summary of Data
from Run CT-256-8 |
Appendix D: Summary of Data
from Run CT-256-9 |
Appendix E: Summary of Data
from Run CT-256-11 |
Section 15 595kb |
Appendix F: Summary of Data
from Run CT-256-12 |
Appendix G: Summary of Data
from Run CT-256-13 |
Appendix H: Summary of
Fischer-Tropsch Catalysts |
Appendix I: Summary
of Slurry Fischer-Tropsch Product Breakdowns |