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Conversion of Cellulosic Wastes to Liquid Hydrocarbon Fuels
Vol. 4, Slurry Phase Synthesis of Liquid Hydrocarbon
Fuels from Biomass
Pyrolysis Gas Using Iron Catalysts
Final Report - 1986
Kuester, James L.
Arizona State University
Table of Contents
List of Tables |
vii |
|
List of Figures |
ix |
|
I |
Introduction |
1 |
|
II |
Review of the Fischer-Tropsch Synthesis |
9 |
|
1 |
Historical Perspective |
9 |
2 |
Reactions and Thermodynamics |
11 |
3 |
Hydrocarbon Product Distributions |
21 |
4 |
Catalysts |
23 |
5 |
Reactors |
28 |
|
III |
Equipment and Procedures |
34 |
|
1 |
Experimental Equipment |
34 |
2 |
Analytical Equipment |
38 |
3 |
Catalyst Preparation |
40 |
4 |
Operating Procedures |
41 |
5 |
Laboratory Safety |
43 |
6 |
Experimental Plan |
44 |
|
IV |
Results and Discussion |
48 |
|
1 |
Catalyst Testing |
48 |
2 |
Slurry Liquid Testing |
66 |
3 |
Factor Study |
73 |
4 |
Optimization |
80 |
|
V |
Summary and Recommendations |
92 |
|
Literature Cited |
100 |
|
Appendix |
A. |
Calculation of Gas Chromatograph Response
Factors |
104 |
B. |
Aqueous Phase Product Analysis |
109 |
C. |
Organic Phase Product Analysis |
112 |
D. |
Catalyst Preparation |
115 |
|