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Mechanistic Studies of Carbon Monoxide Reduction,
Progress Report, January 1, 1985 to June 1, 1987

Gregory L. Geoffroy

Pennsylvania State University

In this pdf format, this document has 18 pages and is 862kb.

Table of Contents

Personnel

3

Narrative 5

A

Transformation of Ketene Ligans into Enolate, Vinyl, and Acetyl Ligands 6
B Isocyanide Induced Ketene Formation 8
C Proton Induced u-CH2 to CH3 Conversion 8
D Hetrobimetallic u-Methylene and u-ketene Complexes 9
E Halide Promoted Formation and Carbonylation of Nitrene Ligands 11
F Formation of Imidates, Amides, Amines, Carbametes and Ureas from the u3-NPh Ligands of Fe3(U3-NPh)2(CO)3 13

G

Miscellaneous Studies Related to Nitrene Clusters 14

References

16
Figures 18