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Development of Novel Active Transport Membrane Devices Phase 1 Final Report - 1994

Laciak, Daniel V.
Quinn, Robert
 Choe, George S.
Cook, Philip J.
 Tsai, Fu-Jya

In the pdf format this document has 172 pages and 6.65MB

Pages 1-85 3.84MB

Pages 86-172 2.82MB

Table of Contents

I

Executive Summary

1

II

Program Overview

3

 

1.0

Introduction 3

2.0

Background 4

3.0

Historical Perspective - Air Products Work in AT Membranes 13

4.0

Phase IA Accomplishments 15

5.0

Technical Focus 18

III

Substrate Fiber Development 20
 

1.0

Introduction 20

2.0

Experimental 22

3.0

Result and Discussion 24

4.0

Summary and Recommendations 35

IV

Composite Membrane Development 37
 

1.0

Physical Properties of Coating Solutions 37

2.0

Coatability of Planar Substrate Coupons 41

3.0

Hollow Fiber Module Fabrication and Evaluation 43

4.0

Summary and Recommendations 72

V

Recent Advances in the Development of Active Transport Materials 76
 

1.0

Influence of H2O Vapor on ATM Permeation Properties 76

2.0

Assessment of H2S Reactivity of ATM Membranes 91

3.0

Discovery of New "High Performance" ATMs 103

VI

Process Application Development and Technology Benefits - 109
Upgrading Subquality Natural Gas 109
 

1.0

Computer Modeling of Active Transport Membranes 109

2.0

ATM Process for Upgrading Natural Gas 113

3.0

Recommendations 117

VII

Commercial Opportunities 122
 

1.0

Upgrading Subquality Natural Gas 122

2.0

CO2 - Selective ATM: Other Opportunities 135

3.0

Ammonia-Selective ATM Materials 138

VIII

Technology Development Status and Overall Recommendations 145