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Process for the preparation of C5+ hydrocarbons.
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Patent Number: SU1833355
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Inventor(s): Van Erp Willibrord Adelbert (NL); Post Martin Franciscus Maria (NL)
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Applicant(s): Shell Int Research (NL)
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Requested Patent: SU1833355
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Application Number: EP19900201167 19900508
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Priority Number(s): GB19890011075 19890515
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IPC Classification: B01J23/86; C07C1/04
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EC Classification: C07C1/04D2B, C07C1/04F2
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Equivalents: AU5496490, AU620246, BR9002209, CA2016619, CN1026409B, CN1047275, DE69011405D, DE69011405T, EG19591, ES2058753T, JP3021694, NO902103, NZ233652, OA9210, TR25279, US5037856, ZA9003610
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Application of 11.05.1990
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Priority of ---
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Published: 07.08.1993 in B.I. No. 29
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Abstract
A method is suggested to produce C5+ hydrocarbons by catalytic reaction of carbon monoxide with hydrogen. The method comprises the following stages:
- selection of a catalyst containing 85-100 g cobalt per 1 ml catalyst and 8-13 wt. parts of zirconium per 100 wt. parts of a support selected among silica, alumina, aluminosilicate, or titanium dioxide, having an outer surface area S = 16–40 cm2/ml;
- activation of the catalyst in a flow of hydrogen or hydrogen-containing gas at a temperature of 150-500°C;
- contacting the activated catalyst fixed bed with a mixture of carbon monoxide and hydrogen under the following conditions: F=H2:CO=1.1-1.8, S/F = 12.18-36.36, T = 180-250°C, P = 15-20 bar.
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