Return to Japanese Patent Table of Contents JP6263665 Abstract PURPOSE: To produce methanol, methane, carbon monoxide, etc., by hydrogenating carbon dioxide gas in the presence of a homogeneous liquid-phase reaction catalyst. CONSTITUTION: Methanol, methane, carbon monoxide, etc., are produced by hydrogenating carbon dioxide gas in the presence of a homogeneous liquid-phase reaction catalyst consisting of a combination of a ruthenium carbonyl complex with an iodine compound. Methanol, methane or carbon monoxide useful as a fuel or a chemical synthesis raw material can be produced from carbon dioxide gas exhausted in large quantity from a thermoelectric power plant, cement factory, etc. Since the catalyst is soluble in solvent in contrast with conventional heterogeneous catalyst, it can be used in a liquid-phase reaction system at an easily controllable temperature. |