HYDROCARBONS, UNSATURATED

ACETALDEHYDE, acetic acid, acetic anhydride and acetone from acetylene at the Bunawerke, Schkopau, the production of, reported by W. L. Wood

199

50 ‘20-50 ‘35

ACETYLENE, absorption of

32-II

195..1541

“ -air explosions, preventing of, by addition of CO₂ or N₂

32-I

127.1045-127.10**

“ and acetone, calculation on the production of

65

Sec. III

25..205-25..21*

“ and amines, products formed by interaction of, reported by J. D. Rose

227

20 ‘83-20 ‘88

“ and carbon monoxide chemistry, new facts from the

65

Sec. III

31..234-31..23*

“ and some of its derivatives, properties of

32-I

169.1392-169.14**

“ , 70%, and synthesis gas by partial combus-tion, cost estimate for production of

65

Sec. III

23..134-23..16*

“ , arc, and of acetaldehyde from it, preliminary estimate of costs of

56

13-60

82-120

“ , arc process for

54

376-389

“ , arc process, production reports, monthly reports, technical difficulties, equipment. January 1942 to April 1945, Huls

154

715-903

ACETYLENE, arc, the present status of production and conversion of

24

12..508-12..568

Article completed

25

12..569-12..625

“ “ , 1939

154

391-508

“ basis, the synthesis of intermediates for polyamides on an, by Reppe. Reported by J. D. Rose.

227

30 ‘17-30 ‘27

“ burner, how to operate the

65

Sec. III

24..165-24..195

“ burners

131

10 ‘1

“ (butenediol production), conference on safety in handling

32-I

123.1025-123.1029

“ chemistry, excerpts from Reppe’s

193

23416-23425

“ chemistry flowsheet, according to Reppe

119

90 ‘77-90 ‘78

di-ACETYLENE chemistry, short memo on development of, at Hüls, April 29, 1943

65

Sec. III

28..227-28..230

ACETYLENE chemistry, Walter Reppe personal history and his contributions in the field of

69

481-524

“ , chlorine and sulfur content of Ludwigshafen (606)

32-I

122.1023-122.1024

“ cleaning plant, flowsheet of, Deutsche Ton and Steinzeugwerke A. G., H 9998

195

30920, 30921

“ , combustion rate of, by Dr. Sachsse

65

Sec. III

25..196-25..204

“ , commercial production and purification of

32-I

121.1018-121.1022

di-ACETYLENE compounds: preparation of 1.6 diols

154

1-34

ACETYLENE, concentrating of

155

358-372

381-465

“ , conference on safety in handling of, in butenediol production

32-I

123.1025-123.1029

“ content of air

32-I

117..963-117..970

“ , continuous chilling and cooling of calcium carbide, by W. E. Alexander

240

10 ‘20-10 ‘26

“ , converter for hydrogenation of, drawing M-5104-4

85

980

“ -CO₂ mixture, ignition experiments with

32-I

129..1051

“ , cracking of methane to

1

2168

29, 30

10 ‘62-10 ‘63

35-39

10 ‘72-10 ‘81

“ decomposition, conference on

32-I

125.1034-125.1040

“ decomposition, experiments on

32-I

130.1052-130.1057

“ , decomposition of concentrated and dilute, by initial ignition

32-I

131.1058-131.1095

ACETYLENE decomposition, research on, summary report

32-I

118..972-118..10*

“ derivatives, two sheets of

119

90 ‘96-90 ‘97

“ , drying of, (with potassium hydroxide)

32-I

119.1002-119.100*

“ , estimate on production of 12,000 cbm/day from natural gas

50

164-168

“ explosion arresters

32-I

126.1041-26.104*

32-I

128..1050

“ explosion, conference report discussing an, (decomposition in the butenediol reactor at Schkopau)

32-I

120.1005-120.10**

“ , explosion experiments on

27

2077

16..99-16..119

“ fire in the butenediol plant, September 1, 1943, memo on the

32-I

116..960-116..9**

“ for chemical use, purification and drying of, reported by W. E. Alexander

240

10 ‘30-10 ‘42

“ from ethylene and butadiene from acetylene, formation of by high frequency discharge, translation of an article from U.S.S.R. Acad. Sci., 1934, by Balandin, Eidus and Zalogin (in German)

24

12..451-12..45*

“ from hydrocarbon gases by the electric arc, studies on the manufacture of, by T. Yamamoto and T. Konosu

231

20 ‘77-20 ‘86

“ from liquid hydrocarbons

56

2-11

“ from methane, Hungarian plant for

46

721-765

“ from methane, thermal production method for

46

3446

739-740

“ from natural gas, with drawings of a plant

46

741-760

“ generation by dry type generators, reported by W. E. Alexander

240

10 ‘26-10 ‘29

“ , German carbide, cyanamide and cyanide industry. Reported by W. G. McBurney, G. W. Sinclair and H. S. Sutherland

198

20 ‘29-20 ‘56

“ , German techniques for handling in chemical operations, reported by Copland and M. A. Youker

227

60 ‘25-60 ‘140

70 ‘1-70 ‘39

“ hydrogenation and preparation

189

21487-21514

“ , hydrogenation of, Hüls, with flowsheet

176

253-255

“ hydrogenation tests at Piesteritz

32-II

198.1548-198.15**

ACETYLENE, impurities in, May, 1943

31

2078

47..271

“ lines, particularly during air-raids, conference regarding safety in

32-I

115..955-115..959

“ manufacture, Schkopau

191

24982-25014

“ -methane and acetylene-nitrogen mixtures, graphs representing the decomposition of

32-I

113..953-113..954

“ , new technical application of, reported by D. C. Evans

226

50 ‘24-50 ‘58

“ -nitrogen and acetylene-methane mixtures, graphs representing the decomposition of

32-I

113..953-113..954

“ plant, detailed cost estimate for new

65

Sec. III

3..18-3..26

“ , problems of piping

155

373-380

“ process, the Fischer-Ruhrchemie

39

3450

30

40 ‘51-40 ‘53

42

1008-1016

“ production equipment, diagrams and drawings of Hüls

154

939-952

“ , production of, by the arc process, particularly with the use of liquid hydrocarbons as the raw material

24

12..458-12..474

“ , production of, from natural gas and oxygen

1

2168

31-34

10 ’64-10 ‘71

“ , production of, Op. 648 drawings

65

Sec. III

32..239-43..255

“ production, Tatarinov’s method of

176

260-273

“ production, the arc process for, reported by G. M. Morrow

198

20 ‘57-20 ‘64

Supplement, drawings

229

10 ‘79-10 ‘106

209

80356-80384

“ project at Baton Rouge, La.

56

61-81

“ purification installation for 2100 cbm gas/hr.

32-II

196.1542-198.1547

“ , purification of

32-II

194.1539-194.1540

“ , recovery of, from the waste gas from acetylene ketonization

55

701-705

“ , research unit for concentration of

1

2268

40-43

10 ‘82-10 ‘87

“ , studies on the separation of, by T. Yamamoto

231

20 ‘87-20 ‘92

ARC experiments. Technical correspondence and specifications.

154

1051-1192

1193-1330

BUTADIENE by cracking butylene glycol diacetate

32-II

238.1768-238.1779

“ by cracking butylene glycol diformate

32-II

239.1780-239.1783

BUTADIENE by dehydration of 1,4-butylene glycol

32-II

2078

241.1793-241.18**

“ by dehydrogenation

1

2168

5

70 ‘82-70 ‘111

“ by thermal cracking of naphthenes

19

107.1339-107.13**

“ dehydrogenation by way of chlorination

1

2168

5

80 ‘39-80 ‘56

14

1157

“ , detail flowsheet for the manufacture of, Part I; Bruex. Kd 2055.

28

2167

116

“ , detail flowsheet for the manufacture of, Part II; Bruex. Kd 2056.

28

2167

117

“ distillation, arrangement of entire

31

2078

81..332

“ distillation at Schkopau

31

2078

15..148-15..15*

123

80 ‘31-80 ‘40

“ , continuous distillation plant at Schkopau

27

17..121-17..15*

“ and acetylene from ethylene by high frequency discharge, translation of an article from the U.S.S.R. Acad. Sci., 1934, by Balandin, Eidus and Zalogin on the formation of, (in German)

24

12..451-12..45*

“ and related compounds, physical properties of

32-I

168.1385-168.13**

“ , butanediol and butenediol, monthly utilities requirements for

31

2078

11..118

“ distillation, connections of the furan and

119

90 ‘81

90 ‘82-90 ‘84

“ distillation, development of

119

50 ‘79-50 ‘83

“ distillation (equipment layout)

31

2078

75..326

“ distillation, flowsheet for

31

2078

78..329

“ distillation, flowsheet of, (inert gas recovery system)

31

2078

71..322

“ distillation, flowsheet of, (wash tower and degasification)

31

2078

80..331

“ distillation in Ludwigshafen

119

70 ‘45-70 ‘51

“ distillation refrigeration plant, apparatus and piping layout for

31

2078

72..323

“ flowsheet symbols, table of

31

2078

69..316-69..3**

“ fractionation, drawings

28

2077

77-81

77..277-81..2**

“ from acetylene hydrogenation

14

1246

“ from acetylene and formaldehyde

119

60 ‘1-60 ‘10

“ from 1,3-butylene glycol

14

1291-1295

“ from hydro-aromatics. Reported by I. H. Jones

199

70 ‘1-70 ‘4

“ intermediate fraction I

154

162-167

BUTADIENE from mixtures of 1,3 and 1,4 butylene glycol

31

2078

67..302-67..305

“ , general flowsheet for the manufacture of 20,000 tons/yr. of, Bruex, Kd 2008a

28

2167

115

“ , hydrogenation of vinyl acetylene to, with zinc dust and sodium hydroxide and with amalgams

25

12..625-12..635

“ manufacture, correspondence on

54

106-112

“ manufacture (Oppau)

28

2167

50-58

“ manufacture, tankage flowsheet for

31

2078

70..321

“ , methylated, large scale experiments on adhesive rubber from

14

1297-1301

“ , miscellaneous information on, including production reports

154

525-714

“ , molecular volume of

15

2074-2080

“ plant, average retention time of a carbon particle in the

31

2078

7..45-7..51

“ plant building layout

31

2078

76..327-77..328

“ plant, construction costs and iron requirements for a 20,000 te/yr.

30

4..411-4..418

“ plant, construction costs, labor requirements, power and iron calculations for a

30

4..420-4..435

“ plant, enlarging the Auschwitz

1

2168

5

80 ‘1-80 ‘10

“ plant, estimate for a 20,000 te/yr.

1

2168

5

80 ‘11-80 ‘21

80 ‘32

“ plant, flow diagram of a

119

90 ‘85

“ plant, plan and flowsheet of a

1

2168

5

80 ’29-80 ‘33

“ plant, plans for the construction of a, Reppe method

119

70 ‘94-70 ‘101

“ plant, 1943 production report on the yield of catalyst furnaces of the

154

281-288

“ polymerization (Oppau)

28

2167

59-62

“ process, discussion of a new, (1939)

119

90 ‘17-90 ‘20

“ process, new, Reppe

54

467-482

“ production, drawing of equipment pipe lines for aldehyde elimination, pressure washing and measuring vessels

31

2078

73..324

“ production, flowsheet for butyraldehyde destruction

31

2078

84..335

“ , production of

154

507-524

“ , production of, by chlorination of butylene, by Dr. Muller-Cunradi production of, from 1,3 butylene glycol

119

2168

5

80 ’34-80 ‘38

“ , production of, from 1,3 butylene glycol

119

50 ‘1-50 ‘20

BUTADIENE production, piping diagram (operation No. 2)

31

2078

74..325

“ production processes, comparison of construction costs, power and materials requirements for different

30

4..419

“ reactor, drawing

119

90 ‘90-90 ‘92

“ reactor system, flowsheet of

31

2078

82..333

“ reactor system, pipe and instrument layout for high pressure steam system

31

2078

83..334

“ reactors, electrical heating circuit of

31

2078

79.330

“ , recycle, from the Buna polymerization as basis for new manufacturing processes

27

2077

30..209-30..21*

“ sales, comparative measurements of

154

307-314

552-567

“ synthesis

26

3..18-3..43

“ , tetramethyl, polymerization experiments

14

1296

“ , dehydrogenation of butane to produce

30

4..318-4..369

“ , thermodynamic constants of

32-I

167.1359-167.13**

ISOBUTANE, sulfo-chlorination of, Leuna

23

22..573-22..58*

BUTENE, alkylation of, from Fischer plants

14

1269-1271

“ and i-butane yields at the different hydro-genation plants, calculated

214

20 ‘86-20 ‘92

“ and proplene, production of, by chlor-dehydrogenation (chlordehyd)

205

719-725

“ by hydrogenation of acetylene

14

1244

n-BUTENE, calculation of an installation for the production of 18,400 te/yr. of, by way of chlorination and splitting

30

4..370-4..407

BUTENE concentration, isomerization, alkylation and polymerization and butane dehydrogenation, minutes of meeting on

56

617-639

n-BUTENE, dehydrogenation of n-butane to

154

364-390

BUTENE, extraction form C₄-cut with AgNO₃ solution

14

1180-1192

“ , flowsheet for the fractionation of, N 9720a-2

28

2167

106

di-BUTENE, hydrogenation of, N 3707-4

28

2167

25

“ “ , hydrogenation of, N6373b-2

28

2167

26

“ “ , hydrogenation of, N 12419-2

28

2167

27

“ “ , hydrogenation of, (electrical wiring diagram), E 913-2

28

2167

28

BUTENE hydrogenation off-gases, elimination of small amounts of butadiene from

78

30-33

di-iso-BUTENE, hydrogenation of, over iron catalysts

173

839-842

di-BUTENE, hydrogenation of, piping details, N 3462b-1

28

2167

29

BUTENE, increase in H₂SO₄ consumption caused by butadiene in

14

1245, 1247

i-BUTENE, manufacture of, at I. G. Farben-industrie, Oppau. Reported by R. H. Boundy and R. L. Hasche.

196

20 ‘42-20 ‘46

BUTENE, polymerization of and fractionation of polymers, flowsheet for, Kd 2208

28

2167

24

“ , polymerization of, dechlorination of i-butyl chloride, fractionation of polymers, flowsheets for, N 10442-2

28

2167

113

i-BUTENE, preparation of

40

3453

12

0 ‘53-0 ‘54

“ “ production and polymerization flowsheet, also a flowsheet for mersol with SO2 and for the production of mersolat 30

23

3424

13..527-15..529

BUTENE, recovery of lower olefins from paraffin-olefin mixture with silver nitrate solutions, report by Dr. Pohl

86

1535-1567

“ , synthesis of, from acetylene, by T. Yamamoto

231

20 ‘47-20 ‘54

i-BUTENE, uses for

50

844-845

DICHLOROACETYLENE, production of

32-II

2078

210.1645-210.1648

COMPOUNDS with olefinic double bonds, addition reactions of

54

3-44

CYCLO polyolefins

69

422-480

“ “ , by Dr. Reppe

226

30 ‘62-30 ‘79

Appendix

40 ‘36-40 ‘47

“ “ , Interview with Reppe, Schlichting and Kroper, I. G. Farbenindustrie. Reported by G. D. Rose.

227

20 ‘69-20 ‘75

3,6 DIMETHYLHEPTENE-1 and pantacene-1

259

342-345

EHTYLENE and propylene, separation of, at the glycerine plant

30

9..567-9..571

“ by the Hauber process, production costs estimates for

135

20 ‘110-20 ‘116

“ , by thermal cracking or oxygen process

56

5-9

122-139

ETHYLENE, catalytic hydrogenation of acetylene to , Dr. Alexander Wacker Ges. fur Elektrochemische Industrie, Burghausen. Reported by A. Cambron.

239

20 ‘11-20 ‘18

“ -containing gases, the production of, by thermal splitting of ethane or propane and by the separation of the product in a Linde gas separation plant

135

20 ‘57-20 ‘109

“ converter, Leuna M 1410-4, propane and oxygen pipelines to the

195

31772

“ , cost of preparation of pure, at Heydebreck

30

10..658-10..667

“ , direct oxidation of, to ethylene oxide

35

3452

10

60 ‘13-60 ‘43

“ enrichment in the hydrogenated electric are acetylene

174

437-440

“ enrichment, Oppau 1939

3

2168

13

20 ‘60-20 ‘63

“ oxide, flowsheet for production of chlorhydrine and, Leuna M 1416-2

195

31743

“ , flowsheet for the liquefaction of, N 9719-a

28

2167

123

“ , flowsheet of acetylene hydrogenation process, Leuna, M 2326-1

194

30007

“ from ethane by thermal cracking (Hauber method), estimated production cost of

135

XVI

20 ‘101-20 ‘107

Translation by Calif. Res. Corp.

244

70 ‘1

“ from gas, comparison of Leverkusen and Höchsts processes for recovery of

123

Sec. II

47-61

“ from gas, discussion with Lurgi on the absorption of

123

Sec. II

43-46

“ from gas, report on the Linde-Frankl adsorption method for

123

Sec. II

63-65

“ , hydrogenation of acetylene to

123

Sec. II

141-147

“ plant, Linde, flow diagram, 77,245

99

3-4

“ plant, flowsheet of a Hauber

193

23446

“ , preparation and separation of from ethane

189

21431-21457

“ , preparation of

189

21458-21474

21475-21486

“ production from Kogasin II, flowsheet of, Leuna M 4485

195

31783

“ , production of, by the Häuber process (thermal splitting of ethane and separation of ethylene by copper solution), by Hirschbeck

193

23384-23415

ETHYLENE, production of, by thermal cracking and its separation by copper solution

205

958-970

“ , purification of ethane, separation of ethane and

189

21431-21457

“ recovery, experimental, from coke oven gas

24

7..291-7..317

“ recovery of, by fractionation

116

20 ‘55-20 ‘72

“ recovery of, from coke oven gas by scrubbing with benzene

119

10 ‘61-10- ‘63

“ recovery from gas, regenerative plant for

123

Sec. II

149-160

“ , report on starting the activated absorption plant

123

Sec. II

10-34

“ , separation and concentration of, from gas

123

Sec. II

4-7

“ , short notes on the absorption of

123

Sec. II

36-41

68-139

“ thermal splitting plant, flow diagram of

135

20 ‘117-20 ‘119

HEPTANE, preparation and properties of pure

46

3446

1-55

“ -1, preparation of

127

&

1508-1509

128

HEXADECENE-1 and octadecene-1, preparation of

79

2469-2471

127

&

1146-1148

128

“ -1, preparation of

127

&

1335-1336

128

HEXANE-2, preparation of

127

&

1298

128

ISOPRENE, effect of aldehydes on the poly-merization of

119

70 ‘1-70 ‘6

“ , flowsheet for the manufacture of, N 12883-2

28

2167

85

“ from isobutylene and formaldehyde, diolefin synthesis

119

0 ’23-0 ‘51

“ from dimethyl dioxane and/or 1, 3-amylene glycol

14

1291-1295

“ polymerization

119

70 ‘88-70 ‘93

“ , process for the manufacture of

29

23..778-23..781

“ , synthesis of, and polymerization

119

20 ‘71-20 ‘88

METHOXYBUTADIENE from the products of acetylization of crotonic aldehyde, the preparation of

15

2147-2167

22

45..691-45..71*

OCTADECENE-1 and hexadecene-1, preparation of

79

2469-2471

“ -1, preparation of

127

&

1541-1544

128

OLEFINS, absorption of, in solution of cuprous salts, II, by Hauber, July, 1942

135

20 ‘111-20 ‘151

“ , concentrating the, discussion in Merseburg, January 1941

28

2171

3..157-3..164

“ C12-C20 by dehydrogenating or cracking paraffinic raffinates

14

1312

“ , determination of constitution of

42

635

Translation S-72

274

1732

Do.

50

361-366

Translation by M. S. Baer, Humble oil and Refining Co.

243

30 ‘36-30 ‘39

Do.

135

20 ‘111-20 ‘142

Translation by the Calif. Res. Corp.

244

70 ‘6-70 ‘19

“ enrichment by scrubbing with cuprous solution

174

451-456

457-460

“ from paraffins by substitution of halogens and splitting off hydrogen halide

50

878-889

“ , gaseous, separation of from paraffins by solvents

57

205-282

“ hydrocarbons, data for synthesized

259

329-341

“ , isolation and purification of higher molecular weight, from primary oxo products

155

113-114

“ , methods of splitting off chlorine from high molecular weight aliphatic alkyl chlorides without displacement of the double bond, Leuna

23

24..605-24..6**

“ , photochemical addition of HC` to

80

4004-4006

“ , production of, by the dehydration of aliphatic alcohols

155

86-91

“ production of, by dehydrogenation of diesel oil

50

342-352

“ , recovery of volatile, from mixtures with gaseous paraffinic hydrocarbons by selective solvents, with particular reference to normal butylene in admixture with butane

30

9..572-9..65*

OLEFINS, separation of branched and middle position, from end position olefins

47

8-9

“ , separation of, in splitting distillate

127

689-695

736-738

808-810

841-843

880-892

925-928

963-972

1012-1013

128

1149-1157

“ , solvent extraction of light, from olefin-paraffin mixtures

18

3042

40

40..263-40..346

“ , technical production of

55

120-121

PENTACENE-1 and 3, 6-dimethylheptene-1

259

342-345

PROPENE and butene, the production of, by chlordehydrogenation (chlordehyd)

205

719-725

“ and ehtylene, separation of, at the glycerine plant

30

9..567-9..571

“ and propane mixtures, separation of

30

9..552-9..566

174

325-336

“ and propane separation of

29

19..743-19..746

“ , formation of

45

90

204-205

“ , production of, in about 30% liquid mixture by a catalytic stage dehydrogenation

26

7..183-7..185

219

0 ‘56-0 ‘61

“ , recovery of concentrated, from a catalytic dehydrogenation process,

30

9..548-9..551

“ , separation of, from gas mixtures, Ludwigshafen

30

9..544-9..547

“ , separation of, from the gases of the propene converters

29

7..457-7..464

“ , the catalytic dehydrogenation of propane to, by Nowotny

138

XXVI

30 ‘95-30 ‘105

“ , uses for

55

88-89

UNSATURATED hydrocarbons in cracked distillates, investigation of the structure of, by the peracetic acid method, J. Verhens, May 30, 1944

79

2367-2390

Translation by Phill. Petr. Co.

245

40 ‘91-40 ‘107

VINYL acetylenes, explosion experiments with

27

14..50-14..87

32-I

132.1096-132.1111

32-II

225.1705-225.1711

53

584-623