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T.O.M. Microfilm Reel 201

(Original designation LF 99)

Table of Contents

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Hochdruckversuche Laboratories - File of Dr. Simon.  Papers on Hydrogenation, Aromatization, and Paraffin Oxidation.

Source of documents L. Griesheim Central I. G. Library.

Folder No.              S-32/VIII-D-2

S-32/VII-D-1

S-32/VII-D-6

S-29/X-D-3

Filmed by:              JIOA

Date:                       28.1.46

Section I.                Papers on Hydrogenation

Item

1.             Influence of the temperature on the reactions taking place during the hydrogenation of bituminous coal liquefaction middle oil over catalysts 5058, 7846, and 8376.  Frames 1-20

2.             Contribution to the theory of sumpf phase.  Frames 22-24

3.             Benzination of DHD-residue.  Frame 25

4.             Experiments concerned with the testing of the motor behavior of auto hydrogenated polymer gasoline.  Frames 26-28

5.             Report on activities, October 1943.  Frames 29-35

6.             Pressure refining of sumpf gasoline at different temperatures.  Frames 36-39

7.             Experiments on the isomerization n-heptane from normal heptane by means of catalysts 5058 in the rotary autoclave.  Frames 40-41

8.             Gas phase catalysts.  Frames 42-43

9.             Recent investigations into the field of benzination catalysts.  Frames 44-48      

10.           Concerns:  Back flow due to the collapse of a high pressure pipe line.  Frames 49-51

11.           The influence of the products partial pressure on the aromatization of bituminous coal liquefaction middle oil Scholven over alumina-Terrana catalyst 8688.  Frames 52-56

12.           The influence of the nitrogen contents of oils on their capability to be benzinated.  Frames 57-64

13.           Removal of the heat of reaction in gas phase hydrogenation by pumping the circulating gas while hot.  Frames 65-67

14.           The testing of regenerated 6434 catalysts.  Frames 68-69

15.           Experimental basis for the working of heavy oils with solid catalysts.  Frame 70

16.           The influence of sulfur addition on the 250 atms. Aromatization of bituminous coal liquefaction middle oil with alumina Terrana catalyst.  Frame 71

17.           The influence of adding organic nitrogen compounds on the results of benzination of crude oil-gas oil over catalyst 6434.  Frames 72-76

18.           The effects of W, Ni, Co and Fe as active components on alumina pre-hydrogenation catalysts.  Frames 77-85

19.           Our supply of liquid fuels.  Frames 86-104

20.           The mechanism of hydrogenation – catalysis.  Frames 105-108

21.           Gasoline from bituminous coal via fuel oil – Diesel oil.  Estimate.  Frames 109-110

22.                Decreasing and increasing temperature during the hydrogenation of Upper Silesian bituminous coal.  Frames 111-112

23.                Centrifugal experiments with sludge from the tar chamber Brux.  Frames 113-114

24.           The action of sodium sulfide on stripper heavy oil.  Frames 115-116

25.           New benzination catalysts.  Benzination catalysts free from tungsten of the oxide-fluoride of Si, Al, and Fe type.  Frames 117-121

26.           Benzination of P 1203/8376 B-M’ oil over 6434 & 8797.  Frames 121-127

27.           Contribution to the theory of ash-balance.  Frames 128-131

28.           Ash balances of autoclave experiments with bituminous coals.  Frames 132-140

29.           The heating up of cracking residues.  Frames 141-143

30.           Replacement of ammonium chloride with Scholven coal.  Frames 144-146

31.           Analysis of low temperature carbonization residue from shale for their possible use as sumpf phase catalysts.  Frames 147-150

32.           Older hydrogenation experiments with arsenic compounds.  Frames 151-153

33.           Starting of coal hydrogenation in the Sumpf phase.  Frames 154-156

34.           Measurements concerning heat transfer in bituminous coal paste.  Frames 157-158

35.           About the question of the starting temperature.  Frames 159-160

36.           Influence of the nitrogen content on the capability of oils to be benzinated.  Frames 161-163

37.           Note on the production of iso-heptane from normal heptane at 50 atms.  over catalyst 5058 with hydrochloric acid addition.  Frame 164

38.           Isomerization of hydrocarbons.  Frames 165-168

39.           The butane and iso-butane contents in the gases from benzination and aromatization with bleaching earth catalysts.  Frames 169-170

40.           Working of bituminous coal liquefaction middle oil over pre-hydrogenation/7846 W 250, benzination and DHD.  Frames 171-188

41.           The influence of temperature on the results of the prehydrogenation with concentrated and diluted catalysts.                 Frames 189-190

42.           Dehydrogenation and refining of polymer gasoline.  Frames 191-193

43.           Influence of the addition of organic nitrogen compounds on the results of the benzination of crude oil gas over catalyst 6434 II.  Frames 194-196

44.           Requirements in rare metals in the gaseous phase with these production methods for gasoline which are most important at the present time.  Frames 197-204

45.           Influence of the re-cycle ration on the 250 at aromatization of bituminous coal liquefaction middle oil over alumina-Terrana catalyst 8688.  Frames 205-213

46.           The dependence of knocking properties of gasoline and gasoline fractions on the starting material.  Frames 214-222

47.           The behavior of acid and basic components of bituminous coal liquefaction middle oil during the prehydrogenation with alumina catalysts.  Frames 223-227

48.           Working of vacuum distillate from a stripper heavy oil at 600 atm. over solid-bed catalyst for Diesel oil with low pour point.  Frames 228-232

49.           Splitting of heavy stripper oil from bituminous coal over solid-bed catalyst at 250 and 600 atm.  Frames 233-244

50.           Calculations bearing on the question 300 vs. 700 atm.  Frames 245-247

51.           Improvement of the low temperature carbonization yield in the separator.  Frames 249

52.           Testing of some new pre-hydrogenation catalysts.  Frame 250

53.            Prehydrogenation of P 1271 with catalyst 8807/8376 and 8806/8376.  Frames 251-253

54.           Laboratory and industrial experiments aiming at increase in the yield in low temperature carbonization of asphalt containing residues.  Frames 254-257

55.           Relations between coal analyses and behavior during hydrogenation.  Frames 258-262

56.           The influence of the sulfur addition on the benzination over catalysts 6434.  Frames 263-265

57.           Crystallographic report on ammonium sulfotungstate.  Frames 266-268

58.           Experiments in the 1 ltr. Furnace with sulfur as Sumpf phase catalyst.  Frames 269-274

59.           Notes on the splitting effect of WS.  Frame 275

60.           Possible replacement of ammonium chloride in the hydrogenation of Ruhr coal.  Frames 276-278

61.           Influence of the size and density of the catalyst pills on the benzination and prehydrogenation with catalyst 5058.  Frames 279-289

62.           Filtration of sludge with the addition of higher alcohols from the iso-butylalcohol production.  Frames 290-291

63.          Autoclave experiments aiming at the splitting of paraffins with tungsten sulfide by means of hydrogenation.  Frames 292-310

64.           New results concerning the lattice disturbance of the active tungsten sulfide.  Frames 311-315

65.           Experimental results with tungsten catalysts.   Frames 316-319

66.           Tungsten oxides.  Frames 320-325

67.           Research into the principles of catalysis.  Frames 326-327

68.           Addition of sodium sulfide in the hydrogenation of bituminous coal.  Frames 328-355

69.           Sulfur absorption of the unsulfurated Bayer mass under high pressure.  Frames 356-358

70.           Sensitivity to nitrogen and other disturbance. A comparison between catalysts 8797 and 6434.  Frame 359

71.           Extended prehydrogenation tests of bituminous and brown coal liquefaction middle products over catalysts 8376 – 7846 W. 250 without sulfur addition to the products.  Frames 360-367

72.           New benzination catalysts.  Frames 368-381

73.           Catalysts 5058 in combination with catalyst 7846.  Frames 382-384

74.           Experiments in the 1 ltr. Furnace aiming at the splitting of stripper heavy from bituminous coal at 250 atm. with solid-bed, regenerable catalyst.  Frames 385-398

75.           Determination of aromatics in gasoline by light absorption measurements.  Frames 399-400

76.           Production of gasoline from petroleum or propane de-asphalted and de-waxed vacuum residue from German crude oil.  Frames 401-403

77.           Hydrogenation of ld aviation lubricant. (1580)  Frames 404-409

Section II

1.             Conference with OHW at Ludwigshafen on the 25th of October 1943.  Subject: Results obtained with small scale apparatus.  Frames 410-413

2.             Directions for the mode of construction of high pressure hydrogenation chambers.  Frames 414-415

3.             Exchange of experience: Sieve analysis of coal and coal paste.       Frames 416-417

4.             Electric pre-heaters, Chamber 2.  Frames 418-423

5.             Exchange of experience:  electric pre-heaters.  Frames 424-427

6.             Exchange of experience: electric pre-heaters.  Frames 428-429

7.             Questionnaire for collecting the data necessary for calculating gas hydrogenation products.  Frames 430-454

8.             Exchange of experience of Dec. 4, 1941, at Ludwigshafen.  Frames 455-470

9.             Comparison of the working conditions of some hydrogenation plants.  Frame 471

10.           Basic data for the hydrogenation of various crude materials.  Frames 472-474

11.           Calculation of the amount of hy-gas which is likely to accrue in the bituminous coal hydrogenation “Hibernia”.  Frames 475-532

12.           Fuel oil conference at Scholven on 5 Jan. 1942.  Frames 533-535

13.           Fuel oil conference at Gelsenberg on 5 Jan. 1942.  Frames 536-539

14.           Regeneration of bituminous coal paste.  Frames 540-542

15.           Increasing the low temperatures carbonization yield by addition of catalysts and surplus steam.  Frames 543-549

16.           Report on a conference held at the premises of Mineralol-Baugesellschaft Limited Co., Berlin, on the 14th, 2, 1941.  Subject: Coal preparation plants.  Frames 550-554

17.           Conference at Scholven.   Frames 555-560

18.           Heating up by means of super-heated hydrogen.  Frames 561-563

19.           Relief of the Sumpf phase pre-heaters.  Frames 564-575

20.           The chemical composition of the crusts formed in the pre-heaters.  Frames 576-578

21.           Velocities in the high pressure furnaces.  Frames 579-581

22.           The gas circulation in 700 atm hydrogenation chambers, particularly from a point of view of measuring technique.  Frames 582-588

23.           What is to be found in the literature on gas hydrogenation products.  Frames 589-597

24.           Exchange of experience: gas hydrogenation products. Frames 598-611

25.           High pressure experiments.  Frames 612-613

26.           Hydrogen partial pressure in the 7019 gas circulation. Frames 614-623

27.           Comparison of the costs of 7019, 5058 and 6434 chambers.  Frames 624-630

28.           Solubility of the hydrogenation components in the Sumpf phase in the bituminous coal hydrogenation at 700 and 300 atms.  Frames 631-635

29.           Possibility for the production of phenol in the hydrogenation of coal.  Frames 636-637

Section III

1.             Polycyclic aromatics from hydrogenation products.  Frames 638-653

2.             Coronen.  Frames 654-673

3.             Aromatization of bituminous coal liquefaction middle oil Scholven P 1271 at 600 atm. Over the new Welheim catalyst (Lu Nr. 8213) produced at Ludwigshafen.  Frames 674-679

4.             Notes on aromatization at 250 and 600 atms.  Frames 680-687

5.             Behavior or aromatic and aromatic gasolines on the addition of lead tetra ethyl.  Frames 688-692

Section IV

1              Hydrogenation and low temperature carbonization in the field of synthetic motor fuel production.  Frames 693-700

2.             The present status of the low temperature bituminous coal carbonization and plans for enlargement of the GB Chemie.  Frames 701-730

Section V

1.             Ester from the residual acids of paraffin oxidation.  4 short memos/reports.  November 1942.  Frames 731-741.  12 pages.

2.             Experiments aiming at the production of Paraffins from tars and brown coal extracts.  December 2, 1941, and February 2, 1936.  Frames 742-754.  14 pages.

3.             Experiments aiming at the production of paraffins from tars.  February 22, 1936.  Frames 755-759.  6 pages.

4.             Method for the determination of small quantities of dicarboxylic acids in fatty acid mixtures by the use of thallium salts.  Frames 760-765.  7 pages.

5.             Testing of a soft paraffin of the Werschen-Weissenfelzer Braunkohlen A.G. for its suitability for fatty acid production.  February 26, 1940.  Frames 766-773.  9 pages.

6.             Saponification and splitting during the cycle of paraffin oxidation products.  Undated.  Frames 774-782.  10 pages.