|
List of Tables |
vi |
List of Figures |
viii |
Section 1
645kb |
I |
Introduction |
1 |
|
A |
General |
1 |
B |
Objectives of Study |
8 |
Section 2
645kb |
II |
Literature Review |
10 |
|
A |
Molecular Sieve Zeolites |
10 |
|
1) |
Zeolite Synthesis |
10 |
|
a) |
The Mechanism of Zeolite Crystallization |
11 |
Section 3
520kb |
b) |
The Role of Organic Molecules in Molecular Sieve Synthesis |
40 |
Section 4
408kb |
2) |
Structure of Zeolites |
64 |
3) |
Classification of Zeolites |
67 |
B |
Zeolite ZSM-5 |
70 |
|
1) |
Structure of Zeolite ZSM-5 |
70 |
2) |
Synthesis of ZSM-5 |
76 |
3) |
Properties and Uses of Zeolite ZSM-5 |
79 |
|
a) |
Adsorption |
79 |
b) |
Ion-Exchange |
81 |
c) |
Catalytic Properties and Surface Chemistry |
83 |
Section 5
415kb |
4) |
ICI Zeolites |
87 |
|
a) |
Zeolite EU-1 |
87 |
b) |
Zeolite EU-2 |
91 |
C |
The Synthesis of Gasoline |
94 |
|
1) |
Fischer-Tropsch Synthesis |
94 |
2) |
Methanol to Gasoline |
100 |
Section 6
519kb |
3) |
Bifunctional Transition Metal-Zeolite
Catalysts |
110 |
III |
Experimental Methods |
113 |
|
A |
Metal Loading |
113 |
B |
Integrated Zeolite Research Laboratory |
113 |
|
1) |
The LSI-11/23 Computer |
116 |
2) |
Cahn Balance System - Computer Control |
129 |
Section 7
606kb |
3) |
The Cahn Balance System - Pneumatics and
Operation |
134 |
4) |
Computerized Micropilot Plant Reactor |
139 |
|
a) |
On-Line Analysis |
146 |
5) |
Computerized X-Ray Diffraction Facility |
156 |
Section 8
377kb |
IV |
Results and Discussion |
159 |
|
A |
Computerized Research Facility |
159 |
|
1) |
X-Ray Diffraction System |
159 |
2) |
Cahn Balance System |
170 |
Section 9
269kb |
3) |
Micropilot Plant Reactor System |
180 |
B) |
Bifunctional Transition Metal-Zeolite
Catalysts |
192 |
|
1) |
Synthesis of Nu-5 |
192 |
Section 10
322kb |
2) |
Synthesis of Sodium Hexamethonium EU-1 |
200 |
3) |
The Effect of (NH4)2O
in the Synthesis of EU-1
Na2O+(NH4)2O |
206 |
4) |
First Synthesis of EU-1 in a Na-Free System |
211 |
5) |
The Synthesis of EU-2 |
213 |
Section 11
511kb |
6) |
Synthesis of ZSM-5 |
219 |
Section 12
363kb |
C) |
Catalytic Performance of Bifunctional
Catalysts |
242 |
|
1) |
Metals Which Non-Dissociatively Adsorb CO |
242 |
2) |
Metals Which Dissociatively Adsorb CO |
252 |
Section 13
302kb |
V |
Conclusions |
263 |
VI |
References |
265 |
|
VII |
Appendices |
|
A |
Appendix A 399kb |
280 |
B |
Appendix B 53kb |
310 |
C |
Appendix C 725kb |
316 |
D |
Appendix D 181kb |
356 |
E |
Appendix E 154kb |
372 |