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Improved Fischer-Tropsch Catalysts for Indirect Coal Liquefaction.
Final Report - 1989

Wilson Jr., R. B.
Tong, G. T.
Chan, Y. W.
Huang, H. W.
McCarty, J. G.

SRI International

Table of Contents 232kb

Executive Summary 199kb

1

I

Cluster-Derived FTS Catalysts 1015kb

I-1
 

Introduction

I-1

Background

I-5
 

Strategy for Selection of Non-ASF FTS Catalysts

I-5

Review of Synthesis Methods

I-12

Experimental Results

I-14
 

Synthesis

I-14
 

Subtask 1:  Synthesis of Hydridocarbonyl Ruthenium Cluster

I-15

Subtask 2:  Reaction of Hydridocarbonyl Ruthenium Clusters with Alkyl Aluminum

I-16

Subtask 3:  Reaction of Alkyl Aluminum Carbonyl Ruthenium Clusters with the Support

I-17

Subtask 4:  Synthesis of Alkyl Complexes of Ruthenium

I-19

Subtask 5:  Reaction of Alkyl Complexes of Ruthenium with the Support

I-20

Characterization

I-20

Catalysts

I-25
 

Fixed-Bed Reactor

I-25

Slurry Phase

I-27

Discussion

I-27

References

I-31

II

Sulfur Treated Catalysts 1316kb

II-1
 

Introduction

II-1

Background

II-3
 

Selective Poisoning of FTS Catalysts

II-3

Uniform Sulfur Adsorption on FTS Catalysts

II-4

Experimental Results

II-5
 

Catalyst Preparation

II-5

Sulfur Treatment of Precipitated Iron Catalysts

II-7

Sulfur Treatment of Fused Iron Catalysts

II-9

Sulfur Treatment of Cobalt Catalysts

II-12

Characterization and Testing of FTS Catalysts

II-14
 

Experimental Procedures

II-14

FTS Testing of Clean and Sulfur-Treated Fused Iron Catalysts

II-16

FTS Testing of Clean and Sulfur-Treated Cobalt Catalysts

II-25

Clean and Sulfur-Treated Precipitated Iron Catalysts

II-30

Evaluation of Improved FTS Catalysts

II-30

Discussion

II-35

Recommendations

II-39

References

II-41

III

Synthesis of Aromatic Hydrocarbons 736kb

III-1
 

Introduction

III-1

Background

III-2
 

Direct Synthesis of Aromatic Hydrocarbons

III-2

Effect of Promoters of FTS Catalysts

III-4

Carbon Deposition

III-6

Experimental Results

III-7
 

Sulfur Treatment of FTS Catalysts

III-7

Medium-level Sulfur Treatment of Ru/Al2O3 Catalysts

III-7

Discussion

III-11

Conclusions and Recommendations

III-17

References

III-18