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Infrared Spectra of Chemisorbed CO on RH - 1978.
Technical Report No. 8.
J. T. Yates, Jr.
T. M. Duncan
S. D. Worley
R. W. Vaughn
Surface Science Division
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Table of Contents
| Abstract |
6 |
| |
I |
Introduction |
8 |
|
II |
Experimental |
9 |
| |
A |
Adsorption Isotherm |
11 |
|
B |
Infrared Spectra of 12CO Adsorbed on RH |
12 |
|
C |
Desorption of 12CO from RH |
13 |
|
D |
Infrared Spectrum of 13CO Adsorbed on RH |
13 |
|
E |
Infrared Spectrum of Rh(13CO)(12CO) |
14 |
|
F |
Exchange of 13CO(ads) with 12CO(g) |
14 |
|
IV |
Discussion |
15 |
| |
A |
Assignment of IR Spectral Features |
15 |
|
B |
Estimate of the Fraction of Rh Present as Isolated Atoms |
16 |
|
C |
Carbonyl Bonding in Rh(CO)2 |
17 |
|
D |
Isotopic Shift for 13CO-Labeled Species |
18 |
|
E |
Comparison of Isotopic Exchange with Desorption Measurements |
18 |
|
V |
Summary |
19 |
|
VI |
Acknowledgement |
20 |
| References |
21 |
| Figure Captions |
27 |
| 