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Mechanistic Studies Related to the Metal Catalyzed Reductions of Carbon Monoxide to Hydrocarbons.
Progress Report, April 1, 1979 to March 31, 1980

Casey, Charles P.

University of Wisconsin

In this pdf format, this document has 12 pages and is 419kb.

Table of Contents

Abstract 3

I

Neutral Metal Formyl Compounds 4
 

A

Synthesis of Neutral Metal Formyl Compounds

4
B Disproportionation of (C5H5) Re(CO)(NO)(CHO) 6

II

Hydroxymethyl metal compounds 8
 

A

Synthesis of Hydroxymethyl Metal Compounds 8
 

1

Methanolysis of (C5H5)(CO)(NO)ReCO2CH2Re(CO)(NO)(C5H5) 8

2

Hydrolysis of Methoxymethyl Complex (C5H5)Re(NO)(CO)(CH2OCH3) 9

3

Alternate Synthese of (C5H5)Re(CO)(NO)(CH2OH) 10
References 12