Catalytic Ammonia Decomposition for Coal-Derived Fuel Gases Topical Report

Catalytic Ammonia Decomposition for Coal-Derived Fuel Gases Topical Report - 1997

Section 1 695kb	Abstract					iii
	List of Figures					vii
	List of Tables					viii
	Acknowledgements					ix
	Executive Summary					xi
	1	Introduction				1
		1.1	Background			1
		1.2	Objectives			2
		1.3	Scope/Approach of Current Work			2
	2	Thermodynamic Evaluation				5
Section 2 582kb	3	Simultaneous NH₃ and H₂S Removal Tests				7
		3.1	Summary of Results			7
		3.2	High-Pressure Tests at RTI			8
			3.2.1	HTHP Test Facility		8
			3.2.2	Shakedown Test in a Blank Reactor		11
			3.2.3	Testing with Plain Zinc Titanate		12
			3.2.4	Testing with Co-Mo Catalyst Mixed with Zinc Titanate		12
Section 3 687kb	4	High-Temperature Catalytic Decomposition				17
		4.1	Catalysts Selected for Testing			17
		4.2	Screening Tests			17
			4.2.1	Atmospheric-Pressure Tests		17
Section 4 358kb			4.2.2	High Pressure Tests		20
				4.2.2.1	Test Results for HTSR-1 Catalyst	21
				4.2.2.2	Effect on H2S on the Performance of HTSR-1 Catalyst	22
				4.2.2.3	Test Results for C100N Catalyst	22
		4.3	Extended Testing with Simulated Gas			23
		4.4	Field Test with Actual Coal Gasifier Gas			23
			4.4.1	Summary		23
			4.4.2	Equipment Description		24
			4.4.3	Test Conditions and Sampling Procedures		25
			4.4.4	Results		26
			4.4.5	Conclusions		28
	5	Conclusions and Recommendations				29
	6	References				31