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Development Studies on Selected Conversion of Synthesis Gas from Coal to High Octane Gasoline.
Final Report - 1978

Brennan, J. A.
Bell, W. K.
Holland, R. E.
Kuo, J. C. W.
Liederman, D.
Lucki, S. J.
Spannuth, H. A.
Wu, C. T.

Mobil Research and Development Corporation
Paulsboro and Princeton, NJ

Table of Contents

  List of Tables v
List of Figures x
Section 1
675kb
Abstract 1

I

Objective and Scope of Work 2

II

Summary 4

III

Introduction 6

IV

Detailed Description of Technical Progress

8
  A Experimental Equipment and Procedures 8
  1 Task 1 - Exploratory Process Research 8
2 Task 2 - Process Development 14
3 Analytical 19
4 Data Handling 20
5 Task 4 - Studies in Support of Process Development 21
6 Materials 22
Section 2
424kb
B Coal to Gasoline - Mobil Direct Conversion Process 26
C Comparison of Mobil Dirct Conversion and fischer-Tropsch Processes 28
  1 Comparison of Products 28
2 Process and Economic Comparison 30
D Fixed Bed Studies with Developmental Catalyst SG-A-1 37
  1 Task 1 - Exploratory Process Research 37
Section 3
377kb
2 Task 2 - Process Development 47
3 Task 4 - Theoretical Studies in Support of Process Development 56
Section 4
697kb
E Fixed Bed Studies with Developmental Catalyst SG-B-2 64
  1 Task 1 - Exploratory Process Research 64
2 Task 2 - Process Development 64
F Task 4 - Theoretical Studies in Support of Process Research with Fixed Bed Catalysts 80
  1 Heat and Mass Transfer Between Catalyst and Gas Stream 80
2 Heat Loss from Fixed Bed Bench-Scale Unit 87
Section 5
605kb
3 Water-Gas Shift Reaction 90
G Fixed Bed Studies with Developmental SG-C Catalysts 99
1 Task 1 - Exploratory Process Research 99
H Fixed Bed Studies with Methanol/Dimethylether Synthesis Catalysts 111
Section 6
940kb
I Fluid atalysts - Plexiglass Model Flow Studies 117
  1 Catalyst SGF-B-1 119
2 Catalyst SGF-A-2 121
3 Catalyst SGF-A-3 124
4 Catalyst SGF-A-4 126
J Studies with Developmental Fluid Catalyst SGF-B-1 128
  1 Task 1 - Exploratory Process Research 128
Section 7
737kb
2 Task 2 - Process Development 153
3 Task 4 - Theoretical Studies in Support of Process Development - Fluid Bed 170
Section 8
702kb
K Studies with Developmental Fluid Catalyst SGF-A-3 183
  1 Task 1 - Exploratory Process Research 183
2 Task 2 - Process Development 195
3 Task 4 - Theoretical Studies in Support of Process Research 204
  V. References 85kb 204
  Appendices
Appendix A- Typical Material Balance for the Bench-Scale Unit 233kb
Appendix B- Detailed Data Obtained with Developmental Catalysts SG-A-1 313kb
Appendix C- Detailed Data Obtained with Developmental Catalyst SG-B-2 272kb
Appendix D- Detailed Data Obtained With Developmental Catalysts SG-B-3 and SGF-B-1 1588kb
Appendix E- Detailed Data Obtained with Developmental Catalysts SG-A-4 and SGF-A-3 594kb