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Investigation of Sulfur-Tolerant Catalysts for Selective
Synthesis of Hydrocarbon Liquids from Coal-Derived Gases
Quarterly Technical Progress Report For
Period March 19, 1982 to June 18, 1982
Bartholomew,
Calvin H.
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Table of Contents
Disclaimer |
ii |
Foreward |
iii |
List of Tables |
v |
List of Figures |
v |
Abstract |
vi |
|
I |
Objectives and Scope |
1 |
|
A |
Background |
1 |
B |
Objectives |
1 |
C |
Technical Approach |
2 |
II |
Summary of Progress |
8 |
III |
Detailed Description of Technical Progress |
8 |
IV |
Conclusions |
21 |
V |
References |
22 |
Appendix |
23 |
|
LIST OF TABLES |
1 |
Catalyst Preparation
Plans (Task 1) |
3 |
2 |
Experimental Plan |
5 |
3 |
H2, CO, CO2
and O2 uptakes on Iron and Cobalt Catalysts |
11 |
4 |
CO Turnover Number
for Supported Iron and Cobalt Catalysts |
12 |
5 |
Product Selectivities
for Iron and Cobalt Catalyst |
13 |
6 |
Product Distributions
for CoB/SiO2 (CoB-S-101) |
14 |
|
LIST OF FIGURES |
1 |
Schedule of Proposed
Research Activities and Progress |
9 |
2 |
Product Distribution
of CoB-S-101 |
16 |
3 |
Activity of CoB-S-101
versus Time |
17 |
4 |
Normalized Activity
vs. Sulfur Coverage during in situ Poisoning of Fe/B, Co-SiO2
and Fe-K-SiO2 |
19 |
5 |
Normalized Activity
vs. Sulfur Coverage during in situ Poisoning of Fe-SiO2 |
20 |
|