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Chemical Interactions in Multimetal/Zeolite Catalysts.
Progress Report, January 7, 1987 to January 6, 1990

Sachtler, Wolfgang M. H.

Northwestern University, Evanston, Illinois

In this pdf format, this document has 23 pages and is 928kb.

Table of Contents

Abstract 3

1

Formation of isolated metal atoms in sodalite cages 4

2

Different characteristics of Metal/zeolite systems prepared by direct reduction of ions or via isolated atoms 5

3

Rejuvination of Pd/NaY and Pd/HY catalysts by oxidative radioperson of the metal 9
4 Formation of mono- or bimetal particles in zeolites by programmed reductive decomposition of volatile metal complexes 11
5 Cation-cation interaction as a cause of enhanced reducibility 13
6 Formation of metal carbonyl clusters in supercages 14
7 Enhanced catalytic activity of metal particle-proton complexes for hydrocarbon conversion reactions 15
8 Stereoselectivity of catalytic reactions due to geometric constraints of particles in cages 17

Literature References

19