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Search for Chemisorbed HCO: The Interaction of Formaldehyde,
Glyoxal and Atomic Hydrogen + CO with RH - 1981
Yates, J. T., Jr.
Cavanagh,
R. R.
Surface Science Division
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Table of Contents
| Abstract |
4 |
|
I |
Introduction |
5 |
| II |
Experimental |
7 |
| III |
Interaction of Formaldehyde with Al2O3
and with Rh/Al2O3 |
8 |
| |
A |
H2CO Adsorbed on Al2O3 |
8 |
| B |
H2CO Adsorbed on Rh/Al2O3 |
9 |
| C |
Perturbation of Rh-Chemisorbed CO Species by Adsorbates on the
Al2O3 Support |
11 |
| IV |
Interaction of Flyoxal with Al2O3
and with Rh/Al2O3 |
12 |
| |
A |
(HCO)2 Adsorbed on Al2O3 |
12 |
| B |
(HCO)2 Adsorbed on Rh/Al2O3 |
13 |
| V |
Interaction of Molecular and Atomic Hydrogen with CO
Adsorbed on RH |
14 |
| VI |
Discussion |
15 |
| |
A |
The Infrared Spectrum of the HCO Ligand |
15 |
| B |
Lack of Evidence for Production of HCO (ads) from either H2Co
or (HCO)2 on Rh/Al2O3 |
16 |
| C |
Atomic Dueterium + CO (ads). Lack of Evidence for DCO (ads) by
this Route |
17 |
| D |
Interaction of H2CO and (HCO)2 with Rh/Al2O3 |
17 |
| E |
Interaction of H2CO with Al2O3 |
18 |
| F |
Interaction of (HCO)2 with Al2O3 |
20 |
| VII |
Summary |
21 |
| VIII |
Acknowledgements |
22 |
| References |
23 |
| Figure Captions |
24 |
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