TITLE: Low severity upgrading of F-T waxes with solid superacids. Quarterly report. AUTHOR: J. W. Tierney; I. Wender. INST. AUTHOR: Pittsburgh Univ., PA. Dept. of Chemical and Petroleum Engineering. SPONSOR: Department of Energy, Washington, DC. LANGUAGE: English PUB. TYPE: Technical Report PUB. COUNTRY: United States SOURCE: Department of Energy [DE], 1992, 9p. NTIS ORDER NO.: DE93008122INW ABSTRACT: To avoid methane production in F-T synthesis on Fe catalysts, efforts are being made on conversion of synthesis gas to high molecular weight hydrocarbons, such as waxes. Strong acidity of sulfated zirconium oxides, ZrO(sub 2)/SO(sub 4), is being used to pretreat long-chain paraffins with carbon numbers greater than n-C(sub 32). Progress during this period is reported on reactivity of Pt/ZrO(sub 2)/SO(sub 4) for hydrocracking n-C(sub 32) and on effects of hydride donor solvent on hydrocracking of n-C(sub 32). 5 figs. REPORT NUMBER: DOE/PC/91304-T3 CONTRACT NUMBER: FG22-91PC91304 |