TITLE: Technology development for iron Fischer-Tropsch catalysis.  Quarterly technical progress report No. 3, April 1, 1995--June 30, 1995.

INST.  AUTHOR: Kentucky Univ. Research Foundation, Lexington.

SPONSOR: Department of Energy, Washington, DC.

LANGUAGE: English

PUB.  TYPE: Technical Report

PUB.  COUNTRY: United States

SOURCE: Department of Energy [DE],  18 Aug 95,  25p.

NTIS ORDER NO.: DE96003386INW

ABSTRACT:

The objective of this research project is to develop the technology for the production of physically robust iron-based Fischer-Tropsch catalyststhat have suitable activity, selectivity and stability to be used in theslurry phase synthesis reactor development. The catalysts that are developed shall be suitable for testing in the Advanced Fuels Development Facility at LaPorte, Texas, to produce either low- or high-alpha product distributions. Previous work by the offeror has produced a catalyst formulation that is 1.5 times as active as the (openquotes)standard- catalyst(close quotes) developed by German workers for slurry phase synthesis. The proposed work will optimize the catalyst composition and pretreatment operation for this low-alpha catalyst. In parallel, work will be conducted to design a high-alpha iron catalyst this is suitable for slurry phase synthesis. Studies will be conducted to define the chemical phases present at various stages of the pretreatment and synthesis stages and to define the course of these changes. The oxidation/reduction cycles that are anticipated to occur inlarge, commercial reactors will be studied at the laboratory scale. Catalyst performance will be determined for catalysts synthesized in this program for activity, selectivity and aging characteristics. The research is divided into four major topical areas: (a) catalyst preparation and characterization, (b) product characterization, (c) reactor operations, and (d) data assessment.

REPORT  NUMBER: DOE/PC/94055-T3

CONTRACT  NUMBER: AC22-94PC94055