TITLE: Catalyst and process development for synthesis gas conversion to isobutylene. Quarterly report, October 1, 1993--December 31, 1993.

AUTHOR: R. G. Anthony;   A. Akgerman.

INST.  AUTHOR: Texas A and M Univ., College Station. Kinetics, Catalysis, and Reaction Engineering Lab.

SPONSOR: Department of Energy, Washington, DC.

LANGUAGE: English

PUB.  TYPE: Technical Report

PUB.  COUNTRY: United States

SOURCE: Department of Energy [DE],  1994,  40p.

NTIS ORDER NO.: DE94010727INW

ABSTRACT:

The objectives of this project are to develop a new catalyst; the kinetics for this catalyst; reactor models for trickle bed, slurry and fixed bed reactors; and to simulate the performance of fixed bed trickle flow reactors, slurry flow reactors, and fixed bed gas phase reactors for conversion of a hydrogen lean synthesis gas to isobutylene. A hydrogen-lean synthesis gas with a ratio of H(sub 2)/CO of 0.5 to 1.0 is produced from the gasification of coal, lignite, or biomass. Isobutylene is a key reactant in the synthesis of methyl tertiary butyl ether (MTBE) and of isooctanes. MTBE and isooctanes are high octane fuels used to blend with low octane gasolines to raise the octane number required for modern automobiles. The production of these two key octane boosters is limited by the supply of isobutylene. MTBE, when used as an octane enhancer, also decreases the amount of pollutants emitted from the exhaust of an automobile engine.

REPORT  NUMBER: DOE/PC/90045-T9

CONTRACT  NUMBER: AC22-90PC90045