TITLE: Development of precipitated iron catalysts with improved stability. Technical progress report No. 10, December 16, 1989--April 31, 1990.
AUTHOR: H. Abrevaya.
INST. AUTHOR: UOP, Inc., Des Plaines, IL.
SPONSOR: Department of Energy, Washington, DC.
LANGUAGE: English
PUB. TYPE: Technical Report
PUB. COUNTRY: United States
SOURCE: Department of Energy [DE], 6 May 92, 14p.
NTIS ORDER NO.: DE92014630INW
ABSTRACT:
The objective of this program is to identify the chemical principles governing the deactivation of precipitated iron catalysts during Fischer-Tropsch synthesis and to use these chemical principles in the design of catalysts suitable for slurry reactors. The performance targets are 88% CO+H(sub 2) conversion with less than 1% deactivation/day for 1 month and a methane and ethane selectivity of no more than 7% (based on hydrocarbons and oxygenates only) at a space velocity of at least 2 normal liters per hr gram iron (NL/hr/gFe) using a synthesis gas with 0.5--1.0 H(sub 2):Co ratio in a slurry reactor.
REPORT NUMBER: DOE/PC/79812-T7
CONTRACT NUMBER: AC22-87PC79812