Bulletin 612
Carbides, Nitrides, and the Carbonitrides of Iron as Catalysts in the Fischer-Tropsch Synthesis
Shultz,
J.F.
Hofer, L.J.E.
Stein, K.C.
Anderson, R.B.
| In the pdf format this document has 74 pages | |
| 1-19 1085kb | 40-59 1450kb |
| 20-39 1367kb | 60-74 991kb |
Contents
| Page | ||
| Summary |
1 | |
| Introduction |
4 | |
| Preparation of carbides, nitrides, and carbonitrides of iron in catalytic form |
5 | |
| Synthesis tests with carbides of iron |
7 | |
| Fused-iron oxide catalysts converted to Hägg carbide |
7 | |
| Synthesis with fused-iron oxide catalysts converted to cementite |
18 | |
| Thermomagnetic analyses of fused-iron oxide catalysts |
23 | |
| Synthesis tests of carburized precipitated-iron catalysts |
25 | |
| Synthesis tests with nitrides and carbonitrides of iron |
28 | |
| Composition changes of e-iron nitrides during synthesis |
28 | |
| Activity, selectivity, and composition changes of partly nitrided catalysts |
33 | |
| Synthesis tests with iron catalysts converted to e-iron carbonitrides |
36 | |
| Exploratory studies on preparation of iron borides |
41 | |
| Structural and chemical changes in catalysts during pretreatment and synthesis |
43 | |
| Structural changes in reduced-iron catalysts on formation of oxide and interstitial phases |
43 | |
| Structural changes of iron catalysts during pretreatment and synthesis |
47 | |
| Electron and X-ray-diffraction studies of iron Fischer-Tropsch catalysts |
53 | |
| Bibliography |
62 | |
| Appendix A - Preparation and composition of catalysts |
65 | |
| Appendix B - Testing procedures |
66 | |
| Appendix C - Separation of carbon monoxide from synthesis gas |
67 | |
| Appendix D - Constant liquid feed system |
69 | |