Bulletin 612
Carbides, Nitrides, and the Carbonitrides of Iron as Catalysts in the Fischer-Tropsch Synthesis
Shultz,
J.F.
Hofer, L.J.E.
Stein, K.C.
Anderson, R.B.
In the pdf format this document has 74 pages | |
1-19 1085kb | 40-59 1450kb |
20-39 1367kb | 60-74 991kb |
Contents
Page | ||
Summary |
1 | |
Introduction |
4 | |
Preparation of carbides, nitrides, and carbonitrides of iron in catalytic form |
5 | |
Synthesis tests with carbides of iron |
7 | |
Fused-iron oxide catalysts converted to Hägg carbide |
7 | |
Synthesis with fused-iron oxide catalysts converted to cementite |
18 | |
Thermomagnetic analyses of fused-iron oxide catalysts |
23 | |
Synthesis tests of carburized precipitated-iron catalysts |
25 | |
Synthesis tests with nitrides and carbonitrides of iron |
28 | |
Composition changes of e-iron nitrides during synthesis |
28 | |
Activity, selectivity, and composition changes of partly nitrided catalysts |
33 | |
Synthesis tests with iron catalysts converted to e-iron carbonitrides |
36 | |
Exploratory studies on preparation of iron borides |
41 | |
Structural and chemical changes in catalysts during pretreatment and synthesis |
43 | |
Structural changes in reduced-iron catalysts on formation of oxide and interstitial phases |
43 | |
Structural changes of iron catalysts during pretreatment and synthesis |
47 | |
Electron and X-ray-diffraction studies of iron Fischer-Tropsch catalysts |
53 | |
Bibliography |
62 | |
Appendix A - Preparation and composition of catalysts |
65 | |
Appendix B - Testing procedures |
66 | |
Appendix C - Separation of carbon monoxide from synthesis gas |
67 | |
Appendix D - Constant liquid feed system |
69 |