PATENT 3929. WILCOX, W.D. (Oil & Gas Research, Inc.). Carbon Black, Carbon Monoxide, and Hydrogenation From Hydrocarbon Gases. United States Patent 2,322,989, June 29, 1943; appl. filed Aug. 11, 1939. Chem. Abs., vol.38, 1944, p. 242. Process is employed for producing C black, CO and CO-O2 gas mixtures having a ratio of the H2 to the CO of 2:1, which involves the steps of pyrolysis within a dissociation chamber, at a temperature of 2,800° -3,000° F., of a hydrocarbon gas to which has been added a volume of CO2<1/2 the volume of the hydrocarbon gas, separation of the resultant gas mixture, and the C particles not retained within the chamber and then introducing into the chamber a volume of CO2 which together with the CO2 added in the first step of the process, equals approximately 1/2 the volume of the hydrocarbon gas, and treating the CO2 at a high temperature with the residual C to form CO, which is added to the resultant gas mixture obtained in the 1st step. |