PATENT 3884. WEBB, G. M., AND MOEHL, R. W. Catalyst. United States Patent Appl. 584,728, no date. Official Gaz., vol. 665, 1952, p. 1313: Chem. Abs., vol. 47, 1953, p. 11603. Shaped catalysts of good physical strength, useful in hydrogenation-dehydrogenation reactions, are produced by forming an aqueous slurry of a carrier (kieselguhr, clay, or silica gel) with at least 1 H2O-soluble metal salt (NiNO3 or NiSO4) and at least 1 H2O-soluble metal salt whose metal in the oxide form is difficult to reduce (Cr, Al, Mg, or Ca nitrate or sulfate), precipitating the metal carbonates with (NH4)2CO3, separating and drying at 100°-250° F., and calcining at 300°-800° F. The calcined material is mixed with 5 percent by wt. of soap and formed into pellets which are reduced in a H2 atmosphere at 575°-750° F. |