PATENT 3791. ----- [VAIL, W.E..] (E. I. du Pont de Nemours & Co.). Producing Carboxylic Acids Such as Propionic Acid. United States Patent 2,000,053, May 7, 1935; appl. filed Aug. 24, 1931. Serial No. 559,132; 7 claims (Cl. 260-116). Chem. Abs., vol. 29, 1935, p. 4027. Gaseous mixture containing an olefinic hydrocarbon, such as C2H4 (for the production of propionic acid) or C3H6 (for the production of butyric acid) steam, and CO is passed over a metal compound, such as K2CO3, which forms a salt with the carboxylic acid produced (suitably at 300° <700 atm. pressure). See abs. 2010. |