PATENT 3337. SHANKLAND, R. V., SHIELDS, S. E., AND THIELE, E. W. (Standard Oil Co. of Indiana). Refining of Synthetic Hydrocarbon Mixtures. United States Patents 2,581,560, Jan. 8, 1952; appl. filed Nov. 8, 1947, Serial No. 784,880; 5 claims (Cl. 260-450). Hydrocarbon mixture obtained by synthesis from CO and H2 consists essentially of hydrocarbons having about 5-20 C atoms per molecule with 0.5-5.0% of combined O. The mixture is characterized by a bad odor and extreme instability toward O2 with a marked tendency toward discoloration and gum formation. The mixture can be refined and purified by treatment with a silica-alumina catalyst of gel structure, containing about 10-25 wt % of Al2O3, at 625°-775° F. and with a severity factor. within the range 0.02-2.0. A catalyst-oil-weight ratio of about 2:1 to 5:1 is employed, and a weight space velocity of about 2-lb. of catalyst. |