PATENTS

3155.----- [RUHRCHEMIE, A. G.]  [Production of Oxygenated Derivatives of Aliphatic Hydrocarbons.]  French Patent 869,163, Jan. 26, 1942:  appl. filed Jan. 10, 1941.  Chem. Zentralb., 1942, I, p. 3039.

Fatty acids and alcohols are formed by the catalytic reaction CO and H2 on olefins, which have first been fractionated.  Example:  A mixture of olefins b. 150°-350° is broken down into 4 fractions.  (1) 165°-220°=olefins C10-C12;  (2) 220°-255°=olefins C13-C14;  (3) 255°-295°=olefins  C15-C16;  (4) 295°-330°=olefins C17-C19.  The aldehydes ad alcohols thus obtained are easily oxidized to fatty acids.  The products possess a high degree of purity.

See also United States Patent 2,415,102 (abs 1991).