PATENTS

PACE, B. S. See abs. 2641, 2642.

PAGE, R. See abs. 891, 892, 893.

2569. PAGE, R., AND THOMAS, E. B. (Celanese Corp. of America). Catalyst for Methane Production From Carbon Monoxide and Hydrogen. United States Patent 2,151,329, Mar. 21, 1939; appl. filed Oct. 20, 1936 (Cl. 23-237). Chem. Abs., vol. 33, 1939, p. 5002.

Catalyst is prepared by precipitating Ni and Al hydroxides from a solution of their nitrates containing 4 times as much Ni nitrate as Al nitrate, the washed precipitate is formed into a shaped mass and dried, all these operations being conducted at a temperature < 30°, and the Ni hydroxide is subsequently reduced at a temperature of about 250°. Example: A mixture of CO and coal gas is treated for removal of S. The resulting gas consisting mainly of CO, H2, and CH4 in proportion of 1:2:1, still containing about 45 mg. S per 1. is passed over the catalyst at about 350°. The resulting gas contains over 50% CH4.