PATENTS
Catalysts for use in reactions such as that of CO with H2 or steam or in dehydrogenation of compounds such at EtOH are prepared by heating to decomposition a double chromate of a nitrogenous base such as NH4 or pyridine and 1 of the metals Zn, Cu, Cd, Mg, Mn, Ag, and Fe. The catalysts may be rendered more active by leaching with a "weak" acid such as 5-10% HOAc. Examples are given of the production of MeOH and higher alcohols from CO and H2. Preparation of basic ZnNH4 chromate, MnNH4 chromate, and Zn bichromate tetrapyridine described. |