PATENTS
Tail gas from hydrogenation of CO is used for hydrogenation of oxygenated organic compounds. To eliminate CO, the tail gas and steam may be passed over a water-gas shift catalyst such as Ni, Fe-Cr, or Co at 600°-700° F. to form CH4 or CO2. After the aldehyde-ketone conversion, the CH4 and CO4 may be used by recycling the remaining gases to the gas-making step when CH4 is formed, or either to the gas-making or synthesis step when CO2 is formed. 1 literature ref. and 9 U. S. patents cited. KAUFMAN, H. See abs. 1039. |