PATENTS 1432. ------. [I. G. FARBENINDUSTRIE, A. G.] [Process for Producing Liquid Hydrocarbons.] German Patent Appl. -. filed Apr. 2, 1943. TOM Reel 26, item 11, frames 603-606: Meyer Transl. PC-S-II. Fischer-Tropsch. vol. 1. chap. 68, 1948. p. 174. In producing liquid hydrocarbons with > 1 C atom in the molecule by the reduction of CO with H2 in the presence of catalysts like those described in German Patent Appl. I 68,608 (abs. 3261). which contain Fe, Cu, alkali beside large amounts of MgO and Kieselguhr. 1 or more of the components is wholly or partly replaced by fluorine compounds or these are additionally incorporated therein. Example: A catalyst of Fe, Cu, K, and MgO on kieselguhr has the MgO replaced by CaF2. With the same throughput, synthesis gas, and temperature, the CO conversion and the yield per m.3 of gas were both increased and the product contained a greater proportion of high-boiling constituents. |