3765. ZHEMOCHKIN, M. N. [Utilization of the Permanent Gases From the Dry Distillation of Wood for Organic Synthesis. III.] Lesokhim. Prom., vol. 2, No. 9, 1939, pp. 12-14; Chem. Zentralb., 1940, I, p. 1106; Chem. Abs., vol. 35, 1941, p. 7152. Permanent gases are now used for heating. This is uneconomical owing to the low heating value, 2,000-3,000 cal. per m.3, and high CO2 content, 50%. By passing the gases and steam over Ni catalysts at 800°, CH4+CO2 or H2O giving CO and H2, and 500°, CO+H2O=CO2+H2, a gas is obtained, which, after cooling and removal of CO2, can be used directly for MeOH synthesis. |