3757. YOSHISAKI, H. [Velocity of Decomposition of Cementite.] Sci. Repts. Tôhoku Imp. Univ., Ser. A, vol. 1, No. 1, 1949, p. 63-70; Chem. Abs., vol. 44, 1950, p. 9887. In the conversion of white cast Fe to gray, namely, decomposition of cementite to Fe and graphite, it is assumed that: (1) The reaction occurs selectively at the surfaces of a number of singular points, as reaction nuclei; (2) the number of reaction nuclei diminishes as the reaction continues; and (3) the velocity of movement of a reaction zone in a fixed direction in a homogeneous crystal grain of the reactant does not vary at constant temperature. On the basis of these assumptions, the following empirical equation was derived for the reaction velocity constant as a function of temperature, C, and Si contents: K=5.8 x 1020 C4.0 Si4.3_ T1/2 e_40000/T. YOUNG, D. W. See abs. 3238. YUGUCHI, M. See abs. 1119, 1120. YUKIO, U. See abs. 2019. ZABOLOTSKIĬ, T. V. See abs. 2913. |