3756. YOSHIKAWA, K. [Oxidation of Methane to Carbon Monoxide and Hydrogen.] Bull. Chem. Soc. Japan, vol. 6, 1931, p. 106-110; Sci. Papers Inst. Phys. Chem. Research (Tokyo), vol. 25, 1934, pp. 295-301; Chem. Abs., vol. 25, 1931, p. 3956. Experiments were made by a flow method at 800°-1,000° with and without catalysts on CH4-air and CH4-O2 mixtures. Ni and Co were efficient catalysts and their activity was promoted by adding various oxides. The most efficient catalysts of those studied were Ni-ThO2 and Ni-SiO2. In the presence of these catalysts the reaction, 2 CH4+O2=2 CO+4 H2, proceeds almost quantitatively at 850°-900°. Without catalysts most of the CH4 remains unchanged at 1,000°. YOSHIMORI, K. See abs. 2200, 2201, 2202, 2203, 2204, 2205. YOSHIOKA, Y. See abs. 1897, 1898, 1899. |