3690. WIETZEL, G. [Preparation of Synthetic Fatty Acids for the Manufacture of Soap.] Klepzig’s Textil-Ztschr., vol. 41, 1938, pp. 528-529; Chem. Abs., vol. 32, 1938, p. 9537. Air is passed for 10-30 hr. through liquid paraffin at 90°-160° in the presence of suitable catalysts. The oxidized product is washed first with an aqueous solvent and later with a base. Any ingredients that cannot be saponified are removed either by extraction with a solvent or by distillation. The crude soap is treated with a diluted acid to liberate the fatty acid, which is then fractionally distilled. Soft soap, soap powder, household soap, and toilet soap can be obtained in this way. |