3607. WATANABE, S., MORIKAWA, K., AND IGAWA, S. Synthesis of Benzine (Gasoline) From Carbon Monoxide by Means of Catalytic Reduction at Atmospheric Pressure. I. Methods of Synthesis and Analysis. Jour. Soc. chem. Ind. (Japan), vol. 37, 1934, B, pp. 142-146; Chem. Abs., vol. 28, 1934, p. 5648. Experimental apparatus and procedure and the catalysts used are described. Experimental results are reported for reductions under the following conditions: (1) 197°, (2) 197° and 203°, and (3) 197° and 228°, with 32.9% CO and 63.8% H2 in the raw gas for (1) and (2) and 32.7% CO and 64.5% H2 for (3). The catalysts for the 3 runs had the compositions: Co:Cu:Th=8:1:0.3 for (1), and Co:Cu:ThO=9:1:2 for (2) and (3). Gasoline yields varied 50-65 mg. per l. of gas for (1), 51-76 mg. per l. for (2) and 36-115 mg. per l. for (3). Material balances for 2 runs are appended. |