3561. ---------------. [VIGNON, L.] [Formation of Hydrocarbons From Carbon Monoxide.] Bull. soc. chim. (4), vol. 9, 1911, pp. 18-20; Chem. Abs., vol. 5, 1911, p. 1088. CO is converted into CH4 by conducting CO over a mixture of CaO and Ca(OH)2 at about 400°. The reaction takes place with the intermediate formation of Ca formate, which decomposes to give CH4 and C2H4. This salt at 360°-370° gives a gas containing 20% CO2, 27% CO, 51% H2, and 2% hydrocarbons. |