3557. VELTISTOVA, M. V., DOLGOV, B. N., AND KARPOV, A. Z. [Synthesis of Methanol From Water Gas Under Pressure.] Jour. Chem. Ind. (U.S.S.R.), vol. 10, No. 9, 1934, pp. 24-32; Chem. Abs., vol. 29, 1935, p. 1059. Best catalyst is prepared by mixing ZnO and Cr2O3 and stirring with CrO3 solution to produce 8ZnO·Cr2-O3·CrO3·χH2O. This is heated in a stream of H2O and forms 8ZnO·1.5 Cr2O3. At 390°-400°, 250 atm., and a gas speed of 10,000 l. per hr., this yields 1,150-1,200 gm. of MeOH per l. of catalyst per hr. Pure CO2 and H2 in the ratio 1:2 should be used, and no inert gas or S compound should be present, though H2S can be reversibly desorbed from the catalyst. VENKATESEN, C. See abs. 1189. VERESHCHAGIN, L. F. See abs. 3559. |