3451. ---------------. [TROPSCH, H.] [Manufacture of Butyl Alcohol, Acetone, and Methanol From Corn.] Brennstoff-Chem., vol. 9, 1928, pp. 1-2; Chem. Abs., vol. 22, 1928, p. 2635. Description of the Commercial Solvents Co. process at Peoria, Ill. The mixture of 60% CO2 and 40% H2 liberated during fermentation is washed with water under pressure to bring the proportion to 25% and 75%, respectively, and is then compressed to 300 atm., and passed over a catalyst comprising 97.75% Zn or Mg oxide with 3.25% Fe2O3. From the mixture of 68% MeOH and 32% H2O, pure MeOH is obtained by rectification. Thirteen tons of MeOH are produced per day. |