3316. TAHARA, H., ISHIBASHI, T., AND KODAMA, S. Preparation of Isobutanol From Carbon Monoxide and Hydrogen. III. Influence of Alkali on the Copper-Chromium Oxide Catalyst. Jour. Soc. Chem. Ind. (Japan), vol. 45, suppl. binding, 1942, pp. 90-91; Chem. Abs., vol. 45, 1951, p. 2849. Varying amounts of K2CO3 and other K salts were added to the Cu-Cr (1:4) catalyst. The best yield (37%) of iso-BuOH was obtained with 70 gm. K2CO3 per 100 gm. Cu+Cr. Higher yields of total reaction product were obtained with K2ZnO2 than with K2CO3, but the product contained more H2O. Other K salts gave poorer yields. With 248 gm. K6Mo7O24, only CH4 was recovered. |