3265. ---------------. [STEACIE, E. W. R., AND ELKIN, E. M.] Further Investigations of Catalysts by Liquid Metals. Canadian Jour. Research, vol. 11, 1934, pp. 47-52; Chem. abs., vol. 28, 1934, p. 7132. Kinetics of MeOH decomposition on solid and liquid Zn were examined in greater detail. The order of the reaction lies between zero and ½ on both solid and liquid. The heat of activation is approximately 30,000 cal. per gm.-mol. The reaction is mainly dehydrogenation. Unsuccessful attempts to investigate certain other reactions on liquid metals are described. |