3174. SHIBATA, Z., AND TERASAKI, Y. [Promoting Carburization of Iron by Barium Carbonate.] Nippon Kinzoku Gakukai-Shi, vol. 2, 1938, pp. 187-192; Chem. Abs., vol. 32, 1938, p. 7382. Electrolytic Fe specimen was carburized by CO at 900° for 2 hr. When BaCO3 was placed in the carburizing chamber, it accelerated the carburization. Conclusion: CO gas is adsorbed on the surface of BaCO3 and then decomposed by the reaction: 4 CO=C3O2+CO2. C3O2 is desorbed and partly polymerized and decomposed by the reaction: C3O2=C2+CO. The C2 gas will diffuse into the Fe, and solid solution is formed. SHIFFLER, W. H. See abs. 2771. SHILLING, W. G. See abs. 2578, 2579. SHIMAMURA, K. See abs. 1344, 1345, 1346, 1349, 1350. |