3173. SHIBATA, Z., AND MORI, I. [Reduction Equilibrium Between Metallic Oxide and Hydrogen. I. Measurement of CoO+H2=Co+H2O by New Methods.] Ztschr. anorg. Chem., vol. 212, 1933, pp. 305-316; Chem. Abs., vol. 27, 1933, p. 4468. Equilibrium CoO+H2=Co+H2O was studied at 921°, 821°, 721°, 622°, 522°, and 422°. The relation between the equilibrium constant K and temperature is: log K=(494.191/T)+1.08690. The dissociation pressure of CoO and the equilibrium of H2O gas at 400°-1,000° are calculated. |