3154. SEGER, F. M., DOHERTY, H. G., AND SACHANEN, A. N. Noncatalytic Polymerization of Olefins to Lubricating Oils. Ind. Eng. Chem., vol. 42, 1951, pp. 2446-2452; Chem. Abs., vol. 45, 1951, p. 1757. Thermal, noncatalytic polymerization of 1-olefins produces excellent lubricating oils. Reaction conditions are 600°-650° F., reaction time about 10 hr., and pressures of 250-500 p.s.i. The preferred range of 1-olefins is from hexene to dodecene. Such olefins from any source, as cracked paraffin wax or Fischer-Tropsch products, can be used for the synthesis. |