3147. SCHWARTZ, C., AND ULICH, H. [Specific Heat, Entropy, and Energy of Formation of the Iron Carbide Fe3C.] Arch. Eisenhüttenw., vol. 10, 1936, pp. 11-12; Chem. Abs., vol. 30, 1936, p. 7021. Specific heat of Fe3C can be expressed by 2 equations, 1 below and 1 above the magnetic transformation point; for the range 273.2°-407.1° K. C=16.8-0.028 T cal. per mol., and from 407.1° K. upward C=28.2. The energy of formation is represented by 3 Fea+Cβ-graphite→Fe3C; energy=2,600 cal. per mol. Heat content I and entropy S for temperatures above 407.1° K. (134°) and for 298.2° K. (25°) as base are expressed by 298.2 IT=28.2 T-8575.4; 298.2 I407.1=2906 cal. per mol., 0ST=28.2 In T-137.8; 0S407.1=32.176 cal. per degree per mol. 5 refs. SCHWARZ VON BERGKAMPFE, E. See abs. 340. |